A Study of Phosphorescent Light Emitting Using Cyclometalated Pt(II) Complexes

被引：12
|
作者：
Son, Seokhwan [1 ]
Lee, Hwangyu [1 ]
Kwak, Cheehun [2 ]
Lee, Jihoon [3 ]
Ahn, Hogeun [1 ]
Chung, Minchul [1 ]
机构：
[1] Sunchon Natl Univ, Dept Chem Engn, Sunchon 540742, Jeonnam, South Korea
[2] Sunchon Natl Univ, Dept Chem, Sunchon 540742, Jeonnam, South Korea
[3] Korea Natl Univ Transportat, Dept Polymer Engn, Chungju 380702, Chungbuk, South Korea
来源：
JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY | 2015年 / 15卷 / 07期
关键词：
Platinum; Photoluminescence; (4-(N; N-bis(piridyl)amino)stilbene; OLED; ELECTROGENERATED CHEMILUMINESCENCE; PLATINUM(II) COMPLEXES; LIGANDS; COORDINATION; PHOTOPHYSICS;
D O I：
10.1166/jnn.2015.10356
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The reaction of platinum [Pt(4-(N,N-bis(piridyl)amino)stilbene]Cl-2 with 5,5 ''-(9,9-dioctyl-9H-fluorene-2,7-diyl)di-2,2'-bipyridine, 2,2'-bipyridine, and 1,10-phenathroline affords the following complexes: [(4-(N,N-bis(piridyl)amino)stilbene)Pt(5,5 ''-(9,9-dioctyl-9H-fluorene-2,7-diyl)di-2,2'-bipyridine)] (1), [(4-(N,N-bis(piridyl)amino)stilbene)Pt(2,2'-bipyridine)] (2), and [(4-(N,N-bis(piridyl)amino)stilbene) Pt(1,10-phenathroline)] (3). In this study, new platinum complex compounds were synthesized utilizing the ligand of a 4-(N,N-bis(piridyl)amino)stilbene system. These complexes were analyzed using a H-1(C-13)-NMR, UV-vis and PL spectrophotometer. The maximum wavelengths of complexes 1, 2, and 3 appear at 409 nnn, 410 nm, and 503 nnn, respectively. The quantum yields of these complexes are 0.32 similar to 0.92.
引用
收藏
页码：5338 / 5341
页数：4
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