Electrical Conductivity of Molten Fluoride-Oxide Melts

被引：10

作者：

Redkin, Alexander A. ^{[1
]}

Tkacheva, Olga Yu. ^{[1
]}

机构：

[1] Inst High Temp Electrochem, Ekaterinburg 620219, Russia

来源：

JOURNAL OF CHEMICAL AND ENGINEERING DATA | 2010年 / 55卷 / 05期

关键词：

ALKALINE-EARTH FLUORIDES; BINARY-MIXTURES; CRYOLITE; DENSITY; AL2O3; CAF2; SYSTEMS; CAO;

D O I：

10.1021/je9009255

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

Empirical equations describing the electrical conductivities of fluorides and fluoride oxide mixtures have been obtained. These equations are based on two suppositions: (a) electrical conductivity of ionic molten substances is connected with the electronic structure of the cations; (b) the electrical conductivity of ionic melts can be expressed in terms of molar volume. In molten mixtures, the form of the electrical conductivity isotherm depends on the interaction between the components.

引用

页码：1930 / 1939

页数：10

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