Electrical Conductivity of Molten Fluoride-Oxide Melts

被引：10
|
作者：
Redkin, Alexander A. [1 ]
Tkacheva, Olga Yu. [1 ]
机构：
[1] Inst High Temp Electrochem, Ekaterinburg 620219, Russia
来源：
JOURNAL OF CHEMICAL AND ENGINEERING DATA | 2010年 / 55卷 / 05期
关键词：
ALKALINE-EARTH FLUORIDES; BINARY-MIXTURES; CRYOLITE; DENSITY; AL2O3; CAF2; SYSTEMS; CAO;
D O I：
10.1021/je9009255
中图分类号：
O414.1 [热力学];
学科分类号：
摘要：
Empirical equations describing the electrical conductivities of fluorides and fluoride oxide mixtures have been obtained. These equations are based on two suppositions: (a) electrical conductivity of ionic molten substances is connected with the electronic structure of the cations; (b) the electrical conductivity of ionic melts can be expressed in terms of molar volume. In molten mixtures, the form of the electrical conductivity isotherm depends on the interaction between the components.
引用
收藏
页码：1930 / 1939
页数：10
相关论文
共 50 条
  • [1] Electrical conductivity of molten fluoride-oxide melts with high addition of aluminium fluoride
    Kubinakova, Emilia
    Hives, Jan
    Danielik, Vladimir
    ACTA CHIMICA SLOVACA, 2016, 9 (02): : 141 - 145
  • [2] Diffusion coefficients of hydrogen in fluoride-oxide melts
    Kozhukhar, VY
    Novokhatskii, IA
    ZHURNAL FIZICHESKOI KHIMII, 1996, 70 (11): : 2094 - 2098
  • [3] Diffusion Coefficients of Hydrogen in Fluoride-Oxide Melts
    Russ J Phys Chem, 11 (1940):
  • [4] INFLUENCE OF ALUMINUM AND SILICON ON THE ELECTRICAL-CONDUCTIVITY OF FLUORIDE-OXIDE SLAGS
    VORONOV, VA
    YAKOVLEV, NF
    PROKHOROV, AN
    STRIGACHEV, EM
    RUSSIAN METALLURGY, 1979, (05): : 51 - 53
  • [5] REDUCTION OF PHOSPHORUS BY ALUMINIUM IN FLUORIDE-OXIDE MELTS.
    YAKOVLEV, N.F.
    GASIK, M.I.
    KANDYBKA, V.P.
    1981, V 11 (N 9): : 502 - 504
  • [6] Electrochemical Behavior of Ti in Molten Fluoride-Oxide System
    Yamanaka, Y.
    Morishige, T.
    Takenaka, T.
    MOLTEN SALTS AND IONIC LIQUIDS 19, 2014, 64 (04): : 275 - 283
  • [7] The Electrical Conductivity of Molten Oxide-Fluoride Cryolite Mixtures
    Arkhipov, Pavel
    Tkacheva, Olga
    MATERIALS, 2021, 14 (23)
  • [8] Electrical conductivity of niobium-containing oxide-fluoride melts
    Istomin S.A.
    Krasikov S.A.
    Pastukhov E.A.
    Ryabov V.V.
    Russian Journal of Non-Ferrous Metals, 2007, 48 (02) : 110 - 113
  • [9] Special Features of the Reduction of Phosphorus by Aluminum in Fluoride-oxide Melts.
    Yakovlev, N.F.
    Gasik, M.I.
    Kandybka, V.P.
    Izvestiya Vysshikh Uchebnykh Zavedenij. Chernaya Metallurgiya, 1981, (09): : 17 - 20
  • [10] Electrical conductivity of molten fluoride lanthanum
    Voronin, B.M., 2001, Nauka Ekatarinburg
12345