High resolution soft X-ray absorption spectroscopy for the chemical state analysis of Mn

被引：36

作者：

Kawai, J ^{[1
]}

Mizutani, Y

Sugimura, T

Sai, M

Higuchi, T

Harada, Y

Ishiwata, Y

Fukushima, A

Fujisawa, M

Watanabe, M

Maeda, K

Shin, S

Gohshi, Y

机构：

[1] Kyoto Univ, Dept Mat Sci & Engn, Sakyo Ku, Kyoto 6068501, Japan

[2] Univ Tokyo, Inst Solid State Phys, Synchrotron Radiat Lab, Tanashi, Tokyo 188002, Japan

[3] High Energy Accelerator Res Org, Photon Factory, Inst Mat Struct Sci, Tsukuba, Ibaraki 3050801, Japan

[4] RIKEN, Inst Phys & Chem Res, Wako, Saitama 3050801, Japan

[5] Natl Inst Environm Studies, Tsukuba, Ibaraki 3050053, Japan

来源：

SPECTROCHIMICA ACTA PART B-ATOMIC SPECTROSCOPY | 2000年 / 55卷 / 09期

关键词：

X-ray absorption; XANES; NEXAFS; Mn; soft X-ray spectroscopy;

D O I：

10.1016/S0584-8547(00)00238-X

中图分类号：

O433 [光谱学];

学科分类号：

0703 ; 070302 ;

摘要：

Mn L-2,L-3 X-ray absorption spectra of various manganese compounds were measured using a synchrotron radiation facility. Very high-resolution spectra were obtained. Sharp lines, which were not found before, were observed, and reproducibility was checked using a different beam line in the synchrotron radiation facility. Difference in spectral line shape was observed as the difference of quantum yield method. An unknown sample was measured and the specimen was concluded to be a mixture of two different oxidation states of Mn. The effects on the change of spectral profiles are discussed. (C) 2000 Elsevier Science B.V. All rights reserved.

引用

页码：1385 / 1395

页数：11

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