Conjugated addition reactions of nitroalkanes with electrophilic alkenes in aqueous media

被引：0
|
作者：
Ballini, R [1 ]
Bosica, G [1 ]
机构：
[1] Univ Camerino, Dipartimento Sci Chim, I-62032 Camerino, Italy
来源：
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 1998年 / 1998卷 / 02期
关键词：
water; Michael addition; nitroalkanes; surfactants;
D O I：
10.1002/(SICI)1099-0690(199802)1998:2<355::AID-EJOC355>3.0.CO;2-2
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The Michael reaction of various nitroalkanes 1 with electrophilic alkenes 2 can be performed in NaOH (0.025 - 0.1 M), without any organic solvent. In many cases the presence of cetyltrimethylammonium chloride (CTACl), as cationic surfactant, produces better results. Good yields of the products 3 are obtained even with hindered, and functionalized staring materials.
引用
收藏
页码：355 / 357
页数：3
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