Epoxidized polybutadiene as a thermal stabilizer for poly(3-hydroxybutyrate). I. Effect of epoxidation on the thermal properties of polybutadiene

被引：7
|
作者：
Choi, JY
Lee, JK
Park, WH [1 ]
机构：
[1] Chungnam Natl Univ, Sch Engn, Dept Text Engn, Taejon 305764, South Korea
[2] Kumoh Natl Univ Technol, Dept Polymer Sci & Engn, Kyungbuk 730701, South Korea
来源：
FIBERS AND POLYMERS | 2002年 / 3卷 / 03期
关键词：
polybutadiene; epoxidation; double bond; glass transition temperature; degradation;
D O I：
10.1007/BF02892626
中图分类号：
TB3 [工程材料学]; TS1 [纺织工业、染整工业];
学科分类号：
0805 ; 080502 ; 0821 ;
摘要：
Polybutadiene (PB) was epoxidized to various extents with m-chloroperbenzoic acid (MCPBA) in homogeneous solution. The thermal proper-ties of the epoxidized PBs were investigated by differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA). As a result of epoxidation the glass transition temperature (T-g) of PB increased by approximately 0.8 degreesC for each I mol% of epoxidation. The thermal decomposition of the epoxidised PBs occurred in two-step process, while that of PB exhibited apparent one-step degradation process.
引用
收藏
页码：109 / 112
页数：4
相关论文
共 50 条
  • [31] Thermal history effects on crystallisation and melting of poly (3-hydroxybutyrate)
    Gunaratne, LMWK
    Shanks, RA
    Amarasinghe, G
    THERMOCHIMICA ACTA, 2004, 423 (1-2) : 127 - 135
  • [32] Study of miscibility, crystallization, mechanical properties, and thermal stability of blends of poly(3-hydroxybutyrate) and poly(3-hydroxybutyrate-co-4-hydroxybutyrate)
    Luo, Rongcong
    Xu, Kaitian
    Chen, Guo-Qiang
    JOURNAL OF APPLIED POLYMER SCIENCE, 2007, 105 (06) : 3402 - 3408
  • [33] Study of miscibility, crystallization, mechanical properties, and thermal stability of blends of poly(3-hydroxybutyrate) and poly(3-hydroxybutyrate-co-4- hydroxybutyrate)
    Luo, Rongcong
    Xu, Kaitian
    Chen, Guo-Qiang
    Journal of Applied Polymer Science, 2007, 105 (06): : 3402 - 3408
  • [34] Thermal Stability of Poly(3-Hydroxybutyrate)/Vegetable Fiber Composites
    Cipriano, Pamela Bento
    de Sa, Mayelli Dantas
    Simoes Andrade, Andre L.
    de Carvalho, Laura Hecker
    Canedo, Eduardo Luis
    PROCEEDINGS OF PPS-30: THE 30TH INTERNATIONAL CONFERENCE OF THE POLYMER PROCESSING SOCIETY, 2015, 1664
  • [35] Thermal degradation of plasticized poly(3-hydroxybutyrate) investigated by DSC
    Janigová, I
    Lacík, I
    Chodák, I
    POLYMER DEGRADATION AND STABILITY, 2002, 77 (01) : 35 - 41
  • [36] Determination of multiple thermal degradation mechanisms of poly(3-hydroxybutyrate)
    Ariffin, Hidayah
    Nishida, Haruo
    Shirai, Yoshihito
    Hassan, Mohd Ali
    POLYMER DEGRADATION AND STABILITY, 2008, 93 (08) : 1433 - 1437
  • [37] Thermal behavior of the maleic anhydride modified poly(3-hydroxybutyrate)
    J. L. Souza
    A. F. Santos
    L. Polese
    Marisa S. Crespi
    C. A. Ribeiro
    Journal of Thermal Analysis and Calorimetry, 2007, 87 : 673 - 677
  • [38] Thermal behavior of the maleic anhydride modified poly(3-hydroxybutyrate)
    Souza, J. L.
    Santos, A. F.
    Polese, L.
    Crespi, Marisa S.
    Ribeiro, C. A.
    JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2007, 87 (03) : 673 - 677
  • [39] Thermal degradation and kinetics of poly(3-hydroxybutyrate)/organoclay nanocomposites
    Erceg, Marko
    Kovacic, Tonka
    Klaric, Ivka
    MACROMOLECULAR SYMPOSIA, 2008, 267 : 57 - 62
  • [40] Thermal characterization of the interaction of poly(3-hydroxybutyrate) with maleic anhydride
    Souza, J. L.
    Santos, A. F.
    Crespi, M. S.
    Ribeiro, C. A.
    JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2011, 106 (02) : 453 - 458
12345