In-line Plasma-induced Graft-copolymerization of Pentaerythritol Triacrylate onto Polypropylene

被引：9
|
作者：
Ma, Gui-Qiu [1 ]
Sun, Guan-Kai [1 ]
Ma, Zhe [1 ]
Li, Jing-Qing [1 ]
Sheng, Jing [1 ]
机构：
[1] Tianjin Univ, Inst Adv Polymer Mat, Sch Mat Sci & Engn, Tianjin Key Lab Composite & Funct Mat,Dept Polyme, Tianjin 300350, Peoples R China
来源：
CHINESE JOURNAL OF POLYMER SCIENCE | 2018年 / 36卷 / 08期
基金：
中国国家自然科学基金;
关键词：
Plasma treatment; Melt processing; Graft copolymerization; Pentaerythritol triacrylate; CHAIN BRANCHING POLYPROPYLENE; SURFACE MODIFICATION; POLYMERIZATION; MEMBRANE; RHEOLOGY;
D O I：
10.1007/s10118-018-2023-0
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Pentaerythritol triacrylate (PETA) was successfully grafted onto the plasma-treated isotactic polypropylene (iPP) via the in situ melt processing. The X-ray photoelectron spectroscopy (XPS) results showed that the hydroxyl and carbonyl groups, and peroxides could be generated via plasma treatment. The content of free radical in plasma-treated iPP (PiPP) was measured by 2,2-diphenyl-1-picrylhydrazyl (DPPH). It was found that the resulting peroxides induced the grafting copolymerization of PETA onto iPP, and the grafted PETA promoted the formation of beta-crystal in PiPP, which was evidenced by Fourier transform infrared spectroscopy (FTIR), differential scanning calorimetry (DSC) and wide-angle X-ray diffraction (WAXD) measurements, respectively.
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页码：979 / 983
页数：5
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