Surface modification of CdSeS nanocrystals for polymer hybrid solar cells

被引:2
|
作者
Erdogan, A. [1 ]
Karakaya, C. [2 ,5 ]
Gonce, M. K. [1 ]
Buyukcelebi, S. [1 ]
Yenel, E. [1 ]
Kara, K. [1 ]
Ozcivan, A. N. [3 ]
Can, M. [4 ]
Kus, M. [1 ]
Demic, S. [5 ]
机构
[1] Selcuk Univ, Adv Technol Res & Applicat Ctr, TR-42030 Konya, Turkey
[2] Celal Bayar Univ, Dept Mat Engn, TR-45040 Muradiye, Manisa, Turkey
[3] Izmir Katip Celebi Univ, Dept Elect & Elect Engn, TR-35620 Izmir, Turkey
[4] Izmir Katip Celebi Univ, Dept Engn Sci, TR-35620 Izmir, Turkey
[5] Izmir Katip Celebi Univ, Dept Mat Sci & Engn, TR-35620 Izmir, Turkey
关键词
PERFORMANCE;
D O I
10.1039/c5ra27735c
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
We report the synthesis of fluorene-carbazole derivatives as capping agents for CdSeS nanocrystals and present their performance in polymer hybrid solar cells. CdSeS nanocrystals and different ligands consisting of fluorene and carbazole units were synthesized and characterized. Both oleic acid and pyridine capped CdSeS nanocrystals were used as reference materials in polymer hybrid solar cells. We observed that our synthesized materials show better efficiencies depending on their structures. In comparison with the reference cells consisting of pyridine capped CdSeS nanocrystals, ligand capped CdSeS shows better efficiency due to electron withdrawing and accepting groups in its structure. The reason behind the superiority of our ligands compared to the reference pyridine is the donor and/or acceptor based compatibility of the combined structures and effective surface modification as well.
引用
收藏
页码:27627 / 27631
页数:5
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