Biotechnological production and high potential of furan-based renewable monomers and polymers

被引:55
|
作者
Lalanne, Lucie [1 ,2 ]
Nyanhongo, Gibson S. [2 ]
Guebitz, Georg M. [2 ,3 ]
Pellis, Alessandro [2 ]
机构
[1] Cezeaux Univ Campus, Polytech Clermont Ferrand, Dept Biol Engn, 2 Ave Blaise Pascal, F-63178 Aubiere, France
[2] Univ Nat Resources & Life Sci, Inst Environm Biotechnol, Dept Agrobiotechnol, Konrad Lorenz Str 20, A-3430 Tulln An Der Donau, Austria
[3] Austrian Ctr Ind Biotechnol, Div Enzymes & Polymers, Konrad Lorenz Str 20, A-3430 Tulln An Der Donau, Austria
关键词
Furan derivatives; Biotechnological production; 25-Furandicarboxylic acid; Enzymatic synthesis; Biodegradation; Biobased polyesters; 5-Hydroxymethyl furfural; Enzymatic hydrolysis; Polycondensation; Poly(ethylene furanoate); FURANDICARBOXYLIC ACID FDCA; BIO-BASED FURANS; SELECTIVE OXIDATION; ENZYMATIC POLYMERIZATION; CATALYZED OXIDATION; CARBOXYLIC-ACIDS; 5-HYDROXYMETHYL-2-FURANCARBOXYLIC ACID; LACTIC-ACID; POLYESTERS; HMF;
D O I
10.1016/j.biotechadv.2021.107707
中图分类号
Q81 [生物工程学(生物技术)]; Q93 [微生物学];
学科分类号
071005 ; 0836 ; 090102 ; 100705 ;
摘要
Of the 25 million tons of plastic waste produced every year in Europe, 40% of these are not reused or recycled, thus contributing to environmental pollution, one of the major challenges of the 21st century. Most of these plastics are made of petrochemical-derived polymers which are very difficult to degrade and as a result, a lot of research efforts have been made on more environmentally friendly alternatives. Bio-based monomers, derived from renewable raw materials, constitute a possible solution for the replacement of oil-derived monomers, with furan derivatives that emerged as platform molecules having a great potential for the synthesis of biobased polyesters, polyamides and their copolymers. This review article summarizes the latest developments in biotechnological production of furan compounds that can be used in polymer chemistry as well as in their conversion into polymers. Moreover, the biodegradability of the resulting materials is discussed.
引用
收藏
页数:17
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