Two-Dimensional and Three-Dimensional Lanthanide Coordination Polymers Built from 4-Hydroxypyridine-2,6-dicarboxylic Acid Ligand

被引：13
|
作者：
Sun, Ya-Guang [1 ]
Rong, Shu-Ting [1 ]
Yu, Wan [1 ]
Wu, Yong-Li [1 ]
Ding, Fu [2 ]
Gao, En-Jun [1 ]
Zhang, Wan-Zhong [1 ]
Verpoort, Francis [2 ]
机构：
[1] Shenyang Inst Chem Technol, Lab Coordinat Chem, Shenyang 110142, Peoples R China
[2] Univ Ghent, Dept Inorgan & Phys Chem, B-9000 Ghent, Belgium
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2009年 / 635卷 / 15期
关键词：
Hydrothermal reaction; Lanthanides; Coordination polymers; Luminescence; X-ray diffraction; METAL-ORGANIC FRAMEWORKS; OCTAMERIC WATER CLUSTERS; MAGNETIC-PROPERTIES; COMPLEXES; LUMINESCENT; PHOTOLUMINESCENCE; DESIGN; CHAIN; 2D; CONVERSION;
D O I：
10.1002/zaac.200900110
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
4-Hydroxypyridine-2,6-dicarboxylic acid (H(3)CAM) reacts with Ln(2)O(3)(Ln = La, Ce) or Ln(NO3)(3) (Ln = Sm, Dy, Gd, Ho) in hydrothermal reactions to form a series of lanthanide coordination polymers 1-6. Elemental analysis, IR spectra and X-ray crystal structure analysis were carried Out to determine the composition and crystal structure of 1-6. Compounds 1 and 2 arc isostructural and contain tetranuclear metallic ring unit and 3D framework. 4-6 are isostructural contain 2D network. Furthermore, the photoluminescent properties of 3 and 4 at room temperature were also studied.
引用
收藏
页码：2585 / 2591
页数：7
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