Two-Dimensional and Three-Dimensional Lanthanide Coordination Polymers Built from 4-Hydroxypyridine-2,6-dicarboxylic Acid Ligand

被引：13

作者：

Sun, Ya-Guang ^{[1
]}

Rong, Shu-Ting ^{[1
]}

Yu, Wan ^{[1
]}

Wu, Yong-Li ^{[1
]}

Ding, Fu ^{[2
]}

Gao, En-Jun ^{[1
]}

Zhang, Wan-Zhong ^{[1
]}

Verpoort, Francis ^{[2
]}

机构：

[1] Shenyang Inst Chem Technol, Lab Coordinat Chem, Shenyang 110142, Peoples R China

[2] Univ Ghent, Dept Inorgan & Phys Chem, B-9000 Ghent, Belgium

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2009年 / 635卷 / 15期

关键词：

Hydrothermal reaction; Lanthanides; Coordination polymers; Luminescence; X-ray diffraction; METAL-ORGANIC FRAMEWORKS; OCTAMERIC WATER CLUSTERS; MAGNETIC-PROPERTIES; COMPLEXES; LUMINESCENT; PHOTOLUMINESCENCE; DESIGN; CHAIN; 2D; CONVERSION;

D O I：

10.1002/zaac.200900110

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

4-Hydroxypyridine-2,6-dicarboxylic acid (H(3)CAM) reacts with Ln(2)O(3)(Ln = La, Ce) or Ln(NO3)(3) (Ln = Sm, Dy, Gd, Ho) in hydrothermal reactions to form a series of lanthanide coordination polymers 1-6. Elemental analysis, IR spectra and X-ray crystal structure analysis were carried Out to determine the composition and crystal structure of 1-6. Compounds 1 and 2 arc isostructural and contain tetranuclear metallic ring unit and 3D framework. 4-6 are isostructural contain 2D network. Furthermore, the photoluminescent properties of 3 and 4 at room temperature were also studied.

引用

页码：2585 / 2591

页数：7

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