The kinetics of the reaction between cyclopentene and aqueous hydrogen peroxide under phase-transfer catalysis

被引：5
|
作者：
Meshechkina, A. E. [1 ]
Mel'nik, L. V. [1 ]
Rybina, G. V. [1 ]
Srednev, S. S. [1 ]
Moskvichev, Yu. A. [1 ]
Shevchuk, A. S. [1 ]
机构：
[1] Yaroslavl State Tech Univ, Yaroslavl, Russia
来源：
PETROLEUM CHEMISTRY | 2015年 / 55卷 / 01期
关键词：
cyclopentene; hydrogen peroxide; 1,2-epoxycyclopentane; 1,2-cyclopentanediol; phase-transfer catalysis; kinetics; reaction rate; mathematical model; EPOXIDATION;
D O I：
10.1134/S0965544114030086
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The kinetics of the reaction between cyclopentene and an aqueous solution of hydrogen peroxide under phase-transfer catalysis conditions has been studied. The activation energies of the successive stages of cyclopentene epoxidation to 1,2-epoxycyclopentane and the hydration of the resulting epoxide to 1,2-cyclopentanediol have been found, and the orders of the reactions with respect to the reactants have been determined. A mathematical model of the process that adequately describes the available experimental data in the entire range of reactant concentrations has been proposed.
引用
收藏
页码：51 / 56
页数：6
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