Heptane-soluble ring-closing metathesis catalysts

被引：32
|
作者：
Hongfa, Chayanant
Tian, Jianhua
Bazzi, Hassan S.
Bergbreiter, David E. [1 ]
机构：
[1] Texas A&M Univ, Dept Chem, College Stn, TX 77842 USA
[2] Texas A&M Univ, Dept Chem, Doha, Qatar
来源：
ORGANIC LETTERS | 2007年 / 9卷 / 17期
关键词：
D O I：
10.1021/ol071210k
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Terminally vinyl-functionalized polyisobutylene (PIB) oligomers can be easily transformed into end-functionalized PIB-bound Ru metathesis catalysts. The nonpolar catalysts so prepared can be used as solutions in heptane and recycled by a gravity-based extraction after addition of a heptane-immiscible polar solvent. This paper describes the synthesis and the recycling of a PIB-supported second-generation Hoveyda-Grubbs catalyst for Ru-catalyzed ring-closing metathesis and ring-opening metathesis polymerizations.
引用
收藏
页码：3259 / 3261
页数：3
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