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A highly selective and sensitive fluorescent chemosensor for Fe3+ in physiological aqueous solution
被引:40
|作者:
Hua, J
[1
]
Wang, YG
[1
]
机构:
[1] Zhejiang Univ, Dept Chem, Hangzhou 310027, Peoples R China
关键词:
D O I:
10.1246/cl.2005.98
中图分类号:
O6 [化学];
学科分类号:
0703 ;
摘要:
A novel fluorescent chemosensor in which two aza-18-crown-6 moieties are linked to a coumarin fluorophore has been synthesized for sensing Fe3+. The selective fluorescence enhancement was observed upon binding Fe3+ at physiological conditions (pH=7.4, [NaCl]=0.135M, [KCl]=0.01M), whereas other metal ions, such as Li+, Na+, K+, Mg2+, Ca2+, Cu2+, Zn2+, Co2+, Ni2+, Mn2+, Hg2+ and Pb2+ produced no effect.
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页码:98 / 99
页数:2
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