Alkylation of toluene with methanol on microporous MXH3-XPW12O40 [M=K+, Cs+, NH4+ and Tl+]

被引:4
|
作者
Johnson, K [1 ]
Viswanathan, B [1 ]
Varadarajan, TK [1 ]
机构
[1] Indian Inst Technol, Dept Chem, Madras 600036, Tamil Nadu, India
来源
关键词
microporous; p-xylene; surface acidity;
D O I
10.1007/BF02475413
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Alkylation of toluene was carried out on microporous salts of phosphotungstic acid. Among the systems studied, M2.5H0.5PW12O40 showed maximum catalytic activity, p-Xylene selectivity was evaluated as a function of x. A linear correlation was observed between para-selectivity and number of strong acid sites with strength of H-0 less than or equal to -5.6.
引用
收藏
页码:365 / 370
页数:6
相关论文
共 50 条
  • [41] Synthesis and structure of 12-member ring crown-shaped oxovanadium borophosphate polyanions:: [H3NC2H4NH2C2H4NH2C2H4NH3]4H[M(VO)12-{O3POB(O)2OPO3}6]•nH2O (M = NH4+, K+)
    Zhao, YN
    Shi, Z
    Ding, SH
    Bai, N
    Liu, W
    Zou, YC
    Zhu, GS
    Zhang, P
    Mai, ZH
    Pang, WQ
    CHEMISTRY OF MATERIALS, 2000, 12 (09) : 2550 - 2556
  • [42] Solvent extraction of H3O+, NH4 +, Ag+, K+, Rb+ and Tl+ into nitrobenzene by using cesium dicarbollylcobaltate in the presence of a hexaarylbenzene-based receptor
    Makrlik, E.
    Selucky, P.
    Vanura, P.
    Toman, P.
    Rathore, R.
    JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY, 2011, 287 (02) : 497 - 500
  • [43] COMPLEXATION THERMODYNAMICS OF IMINE-TYPE BIS(BENZOCROWN ETHER)S .1. SANDWICH COMPLEXATION OF K+, RB+, CS+ AND TL+ WITH POLYMETHYLENE AND M-PHENYLENE BRIDGED CARBONYLHYDRAZONES OF 4'-FORMYLBENZO-15-CROWN-5
    GRUTTNER, C
    HOLDT, HJ
    JOURNAL OF INCLUSION PHENOMENA AND MOLECULAR RECOGNITION IN CHEMISTRY, 1993, 16 (03): : 219 - 230
  • [44] Layered and Cubic Semiconductors AGaM′Q4 (A+ = K+, Rb+, Cs+, Tl+; M′4+ = Ge4+, Sn4+; Q2- = S2-, Se2-) and High Third-Harmonic Generation
    Friedrich, Daniel
    Byun, Hye Ryung
    Hao, Shiqiang
    Patel, Shane
    Wolverton, Chris
    Jang, Joon Ik
    Kanatzidis, Mercouri G.
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2020, 142 (41) : 17730 - 17742
  • [45] PREPARATION, CHARACTERIZATION, AND IONIC-CONDUCTIVITY OF NOVEL CRYSTALLINE, MICROPOROUS SILICOGERMANATES, M3HGE7-MSIMO16.XH2O, M = K+, RB+, CS+ 0-LESS-THAN-M-LESS-THAN-3 X = 0-4 .3.
    FENG, SH
    TSAI, MT
    SZU, SP
    GREENBLATT, M
    CHEMISTRY OF MATERIALS, 1992, 4 (02) : 468 - 472
  • [46] Conductometric Studies of Thermodynamics of 1,10-Didecyl-1,10-diaza-18-crown-6 Complexes with Li+, Na+, K+, Cs+, NH4+, Mg2+, and Ca2+ Ions in Acetonitrile, Methanol, and Ethanol Solutions
    Taghdiri, Mehdi
    Payehghadr, Mahmood
    Behjatmanesh-Ardakani, Reza
    Movahhedi, Sirous
    Nourifard, Farzaneh
    JOURNAL OF CHEMISTRY, 2013, 2013
  • [47] Syntheses, crystal structures, and ion-exchange properties of porous titanosilicates, HM(3)Ti(4)O(4)(SiO4)(3)center dot 4H(2)O (M=H+, K+, Cs+), structural analogues of the mineral pharmacosiderite
    Behrens, EA
    Poojary, DM
    Clearfield, A
    CHEMISTRY OF MATERIALS, 1996, 8 (06) : 1236 - 1244
  • [48] Molecular metals based on BEDT-TTF radical cation salts with magnetic metal oxalates as counterions:: β"-(BEDT-TTF)4A[M(C2O4)3]•DMF (A = NH4+, K+; M = CrIII, FeIII)
    Prokhorova, TG
    Khasanov, SS
    Zorina, LV
    Buravov, LI
    Tkacheva, VA
    Baskakov, AA
    Morgunov, RB
    Gener, M
    Canadell, E
    Shibaeva, RR
    Yagubskii, EB
    ADVANCED FUNCTIONAL MATERIALS, 2003, 13 (05) : 403 - 411
  • [49] Thermal behavior of acid phosphate salts Ca2MH7(PO4)4.2H2O (M = K+ NH4+) and CaK3H(PO4)2
    Koleva, V.
    Najkov, K.
    Najdoski, M.
    Stefov, V.
    THERMOCHIMICA ACTA, 2023, 724
  • [50] B-site substitution effects on the mechanical properties of halide perovskites [C4H12N2][BCl3]<middle dot>H2O (B = NH4+; K+)
    Li, Kai
    Li, Zhi-Gang
    Chen, Yong-Qiang
    Li, Wei
    DALTON TRANSACTIONS, 2024, 53 (34) : 14451 - 14456