Alkylation of toluene with methanol on microporous MXH3-XPW12O40 [M=K+, Cs+, NH4+ and Tl+]

被引:4
|
作者
Johnson, K [1 ]
Viswanathan, B [1 ]
Varadarajan, TK [1 ]
机构
[1] Indian Inst Technol, Dept Chem, Madras 600036, Tamil Nadu, India
来源
关键词
microporous; p-xylene; surface acidity;
D O I
10.1007/BF02475413
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Alkylation of toluene was carried out on microporous salts of phosphotungstic acid. Among the systems studied, M2.5H0.5PW12O40 showed maximum catalytic activity, p-Xylene selectivity was evaluated as a function of x. A linear correlation was observed between para-selectivity and number of strong acid sites with strength of H-0 less than or equal to -5.6.
引用
收藏
页码:365 / 370
页数:6
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