Photochemical Addition of Ethers to C60: Synthesis of the Simplest [60]Fullerene/Crown Ether Conjugates

被引：66

作者：

Tzirakis, Manolis D. ^{[1
]}

Orfanopoulos, Michael ^{[1
]}

机构：

[1] Univ Crete, Dept Chem, Iraklion 71003, Crete, Greece

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2010年 / 49卷 / 34期

关键词：

C-H activation; crown ethers; fullerenes; photocatalysis; radical reactions; RAY CRYSTAL-STRUCTURE; REGIOSELECTIVE SYNTHESIS; RADICAL REACTIONS; FULLERENES; ELECTROCHEMISTRY; BISADDUCTS; TRANS-1;

D O I：

10.1002/anie.201002285

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Easy crowning for [60]fullerene: The simplest and hitherto elusive C 60/crown ether conjugates have been prepared through an effective free-radical approach. This approach includes the activation of the otherwise unreactive α-C-H bond in a series of structurally diverse mono- or polyethers and sulfides. This facile method provides an expedient entry into a novel class of fullerene-based materials. (Figure Presented) © 2010 wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：5891 / 5893

页数：3

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