Solubility of Acetoguanamine in Twelve Neat Solvents from 283.15 to 323.15 K

被引:2
|
作者
Yao, Wenzhi [1 ]
Song, Nan [1 ]
Xie, Ju [2 ]
Zhao, Hongkun [2 ]
Li, Xinbao [1 ]
机构
[1] North China Univ Water Resources & Elect Power, Sch Environm & Municipal Engn, Zhengzhou 450046, Henan, Peoples R China
[2] Yangzhou Univ, Coll Chem & Chem Engn, Yangzhou 225002, Jiangsu, Peoples R China
来源
基金
中国国家自然科学基金;
关键词
ORGANIC-SOLVENTS;
D O I
10.1021/acs.jced.9b00593
中图分类号
O414.1 [热力学];
学科分类号
摘要
By using the shake-flask method, the acetoguanamine solubilities in water, acetonitrile, methanol, n-butanol, isopropanol, isobutanol, ethanol, n-propanol, N,N-dimethylformamide (DMF), 1,4-dioxane, ethyl acetate, and ethylene glycol (EG) were acquired over the temperatures from 283.15 to 323.15 K at ambient pressure (p = 101.2 kPa). The mole fraction of acetoguanamine in equilibrated liquor increased as the temperature increased and followed the order in different solvents: DMF > EG > ethyl acetate > 1,4-dioxane > n-butanol > isobutanol > n-propanol > isopropanol > ethanol > methanol > water > acetonitrile. The acquired solubility was correlated via the Apelblat equation. The largest root-mean-square deviation value and largest relative average deviation were, respectively, 28.12 x 10(-6) and 2.38 x 10(-2).
引用
收藏
页码:4546 / 4550
页数:5
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