Design of Thermally Stable Versions of the Burgess Reagent: Stability and Reactivity Study

被引：17
|
作者：
Metcalf, Thomas A.
Simionescu, Razvan
Hudlicky, Tomas [1 ]
机构：
[1] Brock Univ, Dept Chem, St Catharines, ON L2S 3A1, Canada
来源：
JOURNAL OF ORGANIC CHEMISTRY | 2010年 / 75卷 / 10期
基金：
加拿大自然科学与工程研究理事会; 加拿大创新基金会;
关键词：
STEREOSELECTIVE-SYNTHESIS; CHIRAL VERSION; INNER SALT; SULFAMIDES; EPOXIDES; FACILE; ESTERS;
D O I：
10.1021/jo100212n
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Three new versions of the Burgess reagent were synthesized and their thermal stability investigated by NMR. The new reagents exhibited improved reactivity toward epoxides, diols, and vinyl oxiranes as compared with the original version.
引用
收藏
页码：3447 / 3450
页数：4
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