The aim of this paper is to characterise the compounds formed by the ageing of alpha NI(OH)(2) in 5 M KOH at 70 degrees C. The final product of this treatment is known as the beta Ni(OH)(2) phase, but with the ageing period, a progressive change of electrochemical reactivity as well as a textural and structural evolution are observed. The products obtained are stable in time once the ageing is stopped and are not a mere mixture of alpha and beta but single phase nickel hydroxides whose properties are intermediate between those of alpha and beta Ni (OH)(2). Intermediate forms of nickel hydroxide, whose specific features seem to be the crystallites size and the quantity of absorbed nitrate ions, will be called ''badly crystallised beta'' or beta(bc) as proposed by Delmas et al.
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Henan Normal Univ, Coll Chem & Environm Sci, Xinxiang 453007, Peoples R ChinaHenan Normal Univ, Coll Chem & Environm Sci, Xinxiang 453007, Peoples R China
Shangguan, Enbo
Chang, Zhaorong
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Henan Normal Univ, Coll Chem & Environm Sci, Xinxiang 453007, Peoples R ChinaHenan Normal Univ, Coll Chem & Environm Sci, Xinxiang 453007, Peoples R China
Chang, Zhaorong
Tang, Hongwei
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Henan Normal Univ, Coll Chem & Environm Sci, Xinxiang 453007, Peoples R ChinaHenan Normal Univ, Coll Chem & Environm Sci, Xinxiang 453007, Peoples R China
Tang, Hongwei
Yuan, XiaoZi
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Natl Res Council Canada, Inst Fuel Cell Innovat, Vancouver, BC V6T 1W5, CanadaHenan Normal Univ, Coll Chem & Environm Sci, Xinxiang 453007, Peoples R China
Yuan, XiaoZi
Wang, Haijiang
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Natl Res Council Canada, Inst Fuel Cell Innovat, Vancouver, BC V6T 1W5, CanadaHenan Normal Univ, Coll Chem & Environm Sci, Xinxiang 453007, Peoples R China
机构:
Carderock Division, Naval Surface Warfare Center, 10901 New Hampshire Ave., Silver Spring,MD,20903-5640, United StatesCarderock Division, Naval Surface Warfare Center, 10901 New Hampshire Ave., Silver Spring,MD,20903-5640, United States
Mansour, A.N.
Melendres, C.A.
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Argonne National Laboratory, 9700 South Cass Ave., Argonne,IL,60439-8111, United StatesCarderock Division, Naval Surface Warfare Center, 10901 New Hampshire Ave., Silver Spring,MD,20903-5640, United States