Synthesis and Characterization of New Open-Framework Vanadium Tellurite Featuring an Unprecedented (3,7)-Connected Network: K3[(VVO4)(VIVO)4(TeO3)4]•4H2O

被引：3
|
作者：
Huang, Xi-He [1 ]
Huang, Chang-Cang [1 ]
Liu, Dong-Sheng [1 ,2 ]
Liu, Zhong-Qian [1 ]
Wang, Yu-Bo [1 ]
机构：
[1] Fuzhou Univ, Dept Chem, State Key Lab Breeding Base Photocatalysis, Fuzhou 350002, Peoples R China
[2] Jinggangshan Univ, Dept Chem, Jian 343009, Jiangxi, Peoples R China
来源：
CRYSTAL GROWTH & DESIGN | 2010年 / 10卷 / 05期
关键词：
STRUCTURAL-CHARACTERIZATION; CRYSTAL-STRUCTURE; METAL SELENITES; PYROELECTRIC PROPERTIES; HYDROTHERMAL SYNTHESIS; TIN(II) PHOSPHATE; ION-EXCHANGE; MU-OXO; COMPLEX; OXIDE;
D O I：
10.1021/cg900502y
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Hydrothermal reaction of TeO2, V2O5, K2C2O4, H2C2O4 in water yielded a novel vanadium tellurite, K-3[((VO4)-O-V)((VO)-O-IV)(4)(TeO3)(4)]center dot 4H(2)O. The compound exhibits (2)(infinity)[V4Te4O18](4-) puckered anionic layers that are pillared by [VO4](3-) units into a three-dimensional inorganic open framework with unprecedented (3,7)-connected (4(3))(2)(4(6).6(10).8(5)) topology.
引用
收藏
页码：2021 / 2024
页数：4
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