Bis(2,2′-bipyridine)nitratocopper(II) nitrate

被引：9
|
作者：
Marjani, K
Davies, SC
Durrant, MC
Hughes, DL
Khodamorada, N
Samodi, A
机构：
[1] John Innes Ctr Plant Sci Res, Dept Biol Chem, Norwich NR4 7UH, Norfolk, England
[2] Teacher Training Univ, Fac Chem, Tehran 15614, Iran
[3] John Innes Ctr Plant Sci Res, Computat Biol Grp, Norwich NR4 7UH, Norfolk, England
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2005年 / 61卷
关键词：
D O I：
10.1107/S1600536804030788
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The title complex, [Cu(C10H8N2)(2)(NO3)]NO3, is the first reported unsolvated [Cu(bipy)(2)(NO3)]NO3 structure (bipy is 2,2'-bipyridine). The Cu-II atom of the [Cu(bipy)(2)(NO3)](+) complex is six-coordinated, forming a distorted octahedral geometry; bond lengths to the N atoms of the pyridine rings and one of the O atoms of the chelating NO3 ligand lie in the range 1.975 (5)-2.139 (6) Angstrom, with the second O atom from the NO3 ligand less tightly coordinated at a distance of 2.520 (6) Angstrom. The geometry of the CuN2N'2OO' chromophore more closely resembles that of [Cu(bipy)(2)(NO2)](+) complexes than previously reported [Cu(bipy)(2)(NO3)](+) structures.
引用
收藏
页码：M11 / M14
页数：4
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