Cationic ruthenium complexes based on planar polypyridyl ligand 2,4,6-tris (2-pyridyl)-1,3,5-triazine

被引：0
|
作者：
Sharma, S [1 ]
Trivedi, M [1 ]
Chandra, M [1 ]
Pandey, DS [1 ]
机构：
[1] Awadhesh Pratap Singh Univ, Dept Chem, Rewa 486003, India
来源：
INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY | 2004年 / 43卷 / 12期
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中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
New cationic complexes [Ru(kappa(3)-tPtZ)f{(p-FC6H4)(3)P}(2)Cl]BF4, [Ru(kappa(3)-tptz){(p-CH3C6H4)(3)P}(2)Cl]BF4,[Ru(kappa(3)-tptz){(p-ClC6H4)(3)P}(2) Cl]BF4, [Ru(kappa(3)-tptz){(p-CH3OC6H4)(3)P}(2)Cl]BF4, and [Ru(kappa(3)-tptz){p-(CH3)(2)NC6H4)(3)P}(2)Cl]BF4 containing both group 15 donor and a planar polypyridyl ligand are prepared by reaction of RuCl3.xH(2)O with an excess amount of phosphines and 2,4,6-tris(2-pyfidyl)-1,3,5-triazine (tptz) in methanol under refluxing conditions. Tbe complexes have been characterized by elemental analyses and spectral techniques, viz., IR, H-1 NMR, P-31 NMR, FAB-MS and electronic spectral studies.
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页码：2573 / 2577
页数：5
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