Phase equilibrium-driven selective hydrogenation of limonene in high-pressure carbon dioxide

被引：45
|
作者：
Bogel-Lukasik, Ewa [1 ]
Fonseca, Isabel
Bogel-Lukasik, Rafal
Tarasenko, Yuriy A.
da Ponte, Manuel Nunes
Paiva, Alexandre
Brunner, Gerd
机构：
[1] Univ Nova Lisboa, Fac Ciencias & Tecnol, Dept Quim, REQUIMTE,CQFB, P-2829516 Caparica, Portugal
[2] Tech Univ Hamburg, Inst Thermal & Separat Proc, D-21073 Hamburg, Germany
[3] Inst Sorpt & Problems Endoecol, Kiev, Ukraine
来源：
GREEN CHEMISTRY | 2007年 / 9卷 / 05期
关键词：
D O I：
10.1039/b617187g
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Pressure-tuning of selectivity in the hydrogenation of limonene in carbon dioxide was found in biphasic systems, close but below the critical conditions of the reaction mixture, where hydrogen solubility in the liquid is highly dependent on pressure. The subtle effects of pressure on the two-phase region in CO2 + H-2 + a liquid reagent mixtures are essential factors in determining hydrogenation rates and selectivities in high-pressure carbon dioxide.
引用
收藏
页码：427 / 430
页数：4
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