Self-assembled monolayers of branched alkylsilanes on polycrystalline titanium surfaces

被引：0
|
作者：
Cossement, D
Delrue, Y
Mekhalif, Z
Delhalle, J
Hevesi, L
机构：
[1] Fac Univ Notre Dame Paix, Lab Chem Mat Organ, B-5000 Namur, Belgium
[2] Fac Univ Notre Dame Paix, Lab Interdisciplinaire Spect Elect, B-5000 Namur, Belgium
来源：
SURFACE AND INTERFACE ANALYSIS | 2000年 / 30卷 / 01期
关键词：
polycrystalline titanium; dialkyldichlorosilane; alkyltrichlorosilane; x-ray photoelectron spectroscopy; contact angle measurements; surface modification;
D O I：
10.1002/1096-9918(200008)30:1<56::AID-SIA833>3.0.CO;2-O
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The silanization reaction on polycrystalline titanium surfaces has been studied from the point of view of engineering a densely packed chemisorbed layer at the interface. For this purpose methyl-n-octyldichlorosilane (MODCS) and 2-methyl-1-trichlorosilylundecane (2MTCSU) were used and compared with n-toctyltrichlorosilane (OTCS), X-ray photoelectron spectroscopy and contact angle measurements reveal that 2MTCSU forms well covering but not so densely packed monolayers as does OTCS, In contrast to ZMTCSU, MODCS does not provide a proper modification of the surface because of the small amount of molecules chemisorbed on the surface. Copyright (C) 2000 John Wiley & Sons, Ltd.
引用
收藏
页码：56 / 60
页数：5
相关论文
共 50 条
  • [21] Forces between polymer surfaces and self-assembled monolayers
    Singh, Jagdeep
    Whitten, James E.
    [J]. JOURNAL OF MACROMOLECULAR SCIENCE PART A-PURE AND APPLIED CHEMISTRY, 2008, 45 (11): : 884 - 891
  • [22] Fabrication of Nanostructured Surfaces Using Self-Assembled Monolayers
    Bernhard Basnar
    Martin Madera
    Gernot Friedbacher
    Thomas Vallant
    Ulrich Mayer
    Helmuth Hoffmann
    [J]. Microchimica Acta, 2000, 133 : 325 - 329
  • [23] Cationic systems as self-assembled monolayers on gold surfaces
    Ng, YF
    Strutwolf, J
    Garratt, PJ
    Williams, DE
    [J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1999, 464 (02) : 263 - 267
  • [24] Electrochemistry of self-assembled monolayers on metal surfaces.
    Olson, BW
    Russell, DD
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1999, 217 : U463 - U463
  • [25] Interactions of protein mutants with surfaces of self-assembled monolayers
    Mao, G
    Grainger, DW
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1997, 214 : 318 - PHYS
  • [26] Patterning of self-assembled monolayers and biomaterials on solid surfaces
    Craighead, HG
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1999, 217 : U660 - U660
  • [27] Self-assembled monolayers of alkanethiols on clean copper surfaces
    Sung, MM
    Kim, Y
    [J]. BULLETIN OF THE KOREAN CHEMICAL SOCIETY, 2001, 22 (07) : 748 - 752
  • [28] SELF-ASSEMBLED MONOLAYERS AS MODELS FOR ORGANIC-SURFACES
    DUBOIS, LH
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1992, 204 : 92 - PHYS
  • [29] Self-assembled monolayers of alkanethiols on oxidized copper surfaces
    Sung, MM
    Sung, K
    Kim, CG
    Lee, SS
    Kim, Y
    [J]. JOURNAL OF PHYSICAL CHEMISTRY B, 2000, 104 (10): : 2273 - 2277
  • [30] MODELING ORGANIC-SURFACES WITH SELF-ASSEMBLED MONOLAYERS
    BAIN, CD
    WHITESIDES, GM
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1989, 28 (04): : 506 - 512
12345