0D and 1D dimensional structures based on the combination of polyoxometalates, transition metal coordination complexes and organic amines

被引：51

作者：

Shi, Shu-Yun ^{[1
,2
,3
]}

Zou, Yong-Cun ^{[1
,2
]}

Cui, Xiao-Bing ^{[1
,2
]}

Xu, Jia-Ning ^{[1
,2
]}

Wang, Yan ^{[1
,2
]}

Wang, Guo-Wu ^{[1
,2
]}

Yang, Guang-Di ^{[1
,2
]}

Xu, Ji-Qing ^{[1
,2
]}

Wang, Tie-Gang ^{[1
,2
]}

Gao, Zhong-Min ^{[1
,2
]}

机构：

[1] Jilin Univ, Coll Chem, Changchun, Jilin, Peoples R China

[2] Jilin Univ, State Key Lab Inorgan Synth & Preparat Chem, Changchun, Jilin, Peoples R China

[3] Jiling Normal Univ, Dept Environm Engn, Siping, Jilin, Peoples R China

来源：

CRYSTENGCOMM | 2010年 / 12卷 / 07期

关键词：

HYDROTHERMAL SYNTHESIS; 2-DIMENSIONAL FRAMEWORK; CRYSTAL-STRUCTURE; CLUSTERS; ARCHITECTURES; POLYMER; SERIES; SOLIDS;

D O I：

10.1039/b914655e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Five novel heteropolyanions have been synthesized and characterized by IR, UV-vis, XPS spectroscopy, XRD, and elemental analyses. Single-crystal X-ray diffraction analyses reveal that these five compounds represent novel examples of compounds based on the combination of polyoxometalates, transition metal coordination complexes and organic amines. Of which 1, 2 and 3 exhibit 0D structures of polyoxometalate supported transition metal coordination complexes, while 4 and 5 exhibit novel 1D structures constructed from polyoxometalates and transition metal coordination complexes.

引用

页码：2122 / 2128

页数：7

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