FI Catalysts for Olefin Oligomerization and Polymerization: Production of Useful Olefin-Based Materials by Unique Catalysis

被引：21

作者：

Fujita, Terunori ^{[1
]}

Kawai, Koji ^{[2
]}

机构：

[1] Pte Ltd, Mitsui Chem Singapore R&D Ctr, Singapore 117406, Singapore

[2] Mitsui Chem Inc, New Prod Dev Lab, Sodegaura, Chiba 2990265, Japan

来源：

TOPICS IN CATALYSIS | 2014年 / 57卷 / 10-13期

关键词：

Olefin oligomerization; Olefin polymerization; FI catalysts; Olefin-based materials; 1-Hexene; IMINE CHELATE LIGANDS; TRANSITION-METAL-COMPLEXES; BIS(PHENOXY-IMINE) TITANIUM COMPLEXES; METALLOCENE POLYOLEFIN CATALYSTS; LIVING PROPYLENE POLYMERIZATION; MOLECULAR-WEIGHT POLYETHYLENES; HIGH-PERFORMANCE CATALYSTS; ETHYLENE-POLYMERIZATION; ZIRCONIUM COMPLEXES; ZIEGLER-NATTA;

D O I：

10.1007/s11244-014-0246-z

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

This contribution highlights the uniqueness of FI catalysts (phenoxy-imine ligated group 4 metal complexes) for olefin coordination insertion catalysis. FI catalysts possess characteristic structural and electronic features that are different from those of group 4 metallocene catalysts. These special features in turn initiate versatile catalytic properties that result in useful olefin-based materials some of which have already been commercialized.

引用

页码：852 / 877

页数：26

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