ZSM-5 zeolite synthesis in the presence of a copper-phthalocyanine complex Characterization by ESR and 129Xe NMR

被引：5
|
作者：
Gedeon, A
Valeux, M
Gruia, M
Minghua, G
Fraissard, J
机构：
[1] Univ Paris 06, CNRS URA 1428, Lab Chim Surfaces, F-75252 Paris 05, France
[2] Fushun Res Inst Petr & Petrochem Wanghua Fushun, Lianing 113001, Peoples R China
来源：
SOLID STATE NUCLEAR MAGNETIC RESONANCE | 1997年 / 9卷 / 2-4期
关键词：
ZSM-5; zeolite; copper phthalocyanine complex; crystallinity; Xe-129 NMR spectroscopy;
D O I：
10.1016/S0926-2040(97)00070-2
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
In the presence of a copper phthalocyanine complex (CuPc), it is possible to synthesize ZSM-5 zeolite containing the complex, and the crystallinity is good, provided that the amount of CuPc trapped is lower than the number of channel intersections where it can be located without too much distortion. The crystallinity is retained after decomposition of the CuPc in a stream of air at 500 degrees C. The copper-ZSM-5 system is characterized by the combined application of xenon adsorption, ESR and Xe-129 NMR spectroscopy. (C) 1997 Elsevier Science B.V.
引用
收藏
页码：269 / 276
页数：8
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