ZSM-5 zeolite synthesis in the presence of a copper-phthalocyanine complex Characterization by ESR and 129Xe NMR

被引：5
|
作者：
Gedeon, A
Valeux, M
Gruia, M
Minghua, G
Fraissard, J
机构：
[1] Univ Paris 06, CNRS URA 1428, Lab Chim Surfaces, F-75252 Paris 05, France
[2] Fushun Res Inst Petr & Petrochem Wanghua Fushun, Lianing 113001, Peoples R China
来源：
SOLID STATE NUCLEAR MAGNETIC RESONANCE | 1997年 / 9卷 / 2-4期
关键词：
ZSM-5; zeolite; copper phthalocyanine complex; crystallinity; Xe-129 NMR spectroscopy;
D O I：
10.1016/S0926-2040(97)00070-2
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
In the presence of a copper phthalocyanine complex (CuPc), it is possible to synthesize ZSM-5 zeolite containing the complex, and the crystallinity is good, provided that the amount of CuPc trapped is lower than the number of channel intersections where it can be located without too much distortion. The crystallinity is retained after decomposition of the CuPc in a stream of air at 500 degrees C. The copper-ZSM-5 system is characterized by the combined application of xenon adsorption, ESR and Xe-129 NMR spectroscopy. (C) 1997 Elsevier Science B.V.
引用
收藏
页码：269 / 276
页数：8
相关论文
共 50 条
  • [1] Use of ESR and 129Xe NMR spectroscopy to characterize CuZSM-5 zeolite synthesized in the presence of a copper-phthalocyanine complex
    Gédéon, A
    Fraissard, J
    COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 1999, 158 (1-2) : 201 - 206
  • [2] 129Xe NMR study of ZSM-5 type zeolites. Effect of cationic sites
    Univ of Joensuu, Joensuu, Finland
    Microporous Mater, 1-2 (57-62):
  • [3] XE-129-NMR STUDIES OF TYPE NAY, ZSM-5 AND ZSM-20 ZEOLITE CRYSTALLIZATION
    ITO, T
    FRAISSARD, J
    NAGY, JB
    DEWAELE, N
    GABELICA, Z
    NASTRO, A
    DEROUANE, EG
    ZEOLITES : FACTS, FIGURES, FUTURE, PTS A & B, 1989, 49 : 579 - 588
  • [4] Analysis of the Temperature and Pressure Dependence of the 129Xe NMR Chemical Shift and Signal Intensity for the Derivation of Basic Parameters of Adsorption as Applied to Zeolite ZSM-5
    Yoko Kawata
    Yuko Adachi
    Saori Haga
    Junko Fukutomi
    Hirohiko Imai
    Atsuomi Kimura
    Hideaki Fujiwara
    Analytical Sciences, 2007, 23 : 1397 - 1402
  • [5] Analysis of the temperature and pressure dependence of the 129Xe NMR chemical shift and signal intensity for the derivation of basic parameters of adsorption as applied to zeolite ZSM-5
    Kawata, Yoko
    Adachi, Yuko
    Haga, Saori
    Fukutomi, Junko
    Imai, Hirohiko
    Kimura, Atsuomi
    Fujiwara, Hideaki
    ANALYTICAL SCIENCES, 2007, 23 (12) : 1397 - 1402
  • [6] Analysis of NMR Adsorption Isotherms of Zeolite ZSM-5: Adsorption Profiles Derived from the Pressure and Temperature Dependences of 129Xe NMR Chemical Shift and Signal Intensity
    Fujiwara, Hideaki
    Imai, Hirohiko
    Adachi, Yuko
    Kimura, Atsuomi
    Analytical Sciences, 2021, 37 (12): : 1803 - 1810
  • [7] Analysis of NMR Adsorption Isotherms of Zeolite ZSM-5: Adsorption Profiles Derived from the Pressure and Temperature Dependences of 129Xe NMR Chemical Shift and Signal Intensity
    Fujiwara, Hideaki
    Imai, Hirohiko
    Adachi, Yuko
    Kimura, Atsuomi
    ANALYTICAL SCIENCES, 2021, 37 (12) : 1803 - 1810
  • [8] Analysis of NMR Adsorption Isotherms of Zeolite ZSM-5: Adsorption Profiles Derived from the Pressure and Temperature Dependences of 129Xe NMR Chemical Shift and Signal Intensity
    Hideaki Fujiwara
    Hirohiko Imai
    Yuko Adachi
    Atsuomi Kimura
    Analytical Sciences, 2021, 37 : 1803 - 1810
  • [9] Direct observation of the mesopores in ZSM-5 zeolites with hierarchical porous structures by laser-hyperpolarized 129Xe NMR
    Liu, Yong
    Zhang, Weiping
    Liu, Zhicheng
    Xu, Shutao
    Wang, Yangdong
    Xie, Zaiku
    Han, Xiuwen
    Bao, Xinhe
    JOURNAL OF PHYSICAL CHEMISTRY C, 2008, 112 (39): : 15375 - 15381
  • [10] Synthesis and Characterization of Magnetic ZSM-5 Zeolite
    曹吉林
    常贵环
    郭宏飞
    陈建新
    Transactions of Tianjin University, 2013, (05) : 326 - 331
12345