Mechanical and dielectric loss spectroscopy of defects in doped ZrO2

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作者
Weller, M
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O64 [物理化学(理论化学)、化学物理学];
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070304 ; 081704 ;
摘要
The mechanical and dielectric loss spectra of ZrO2-Y2O3 and ZrO2-CaO indicate the presence of associates (dipoles) consisting of dopant cations and oxygen vacancies on nearest neighbour sites, with trigonal defect symmetry. Reorientation of the dipoles is connected with a polarization current, which should be considered in the analysis of AC impedance measurements.
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页码:485 / 490
页数:6
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