Cultivating Fluorescent Flowers with Highly Luminescent Carbon Dots Fabricated by a Double Passivation Method

被引:12
|
作者
Han, Shuai [1 ,2 ]
Chang, Tao [1 ]
Zhao, Haiping [2 ]
Du, Huanhuan [1 ]
Liu, Shan [1 ]
Wu, Baoshuang [1 ]
Qin, Shenjun [2 ]
机构
[1] Hebei Univ Engn, Coll Mat Sci & Engn, Handan 056038, Peoples R China
[2] Hebei Univ Engn, Key Lab Resource Explorat Res Hebei Prov, Handan 056038, Peoples R China
来源
NANOMATERIALS | 2017年 / 7卷 / 07期
关键词
carbon dots; surface passivation; luminescence; Ca(OH)(2); flowers; GRAPHENE QUANTUM DOTS; PHOTOLUMINESCENCE; NANODOTS; NANOPARTICLES; EFFICIENT; TOXICITY; FACILE; STATE;
D O I
10.3390/nano7070176
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
In this work, we present the fabrication of highly luminescent carbon dots (CDs) by a double passivation method with the assistance of Ca(OH)(2). In the reaction process, Ca2+ protects the active functional groups from overconsumption during dehydration and carbonization, and the electron-withdrawing groups on the CD surface are converted to electron-donating groups by the hydroxyl ions. As a result, the fluorescence quantum yield of the CDs was found to increase with increasing Ca(OH)(2) content in the reaction process. A blue-shift optical spectrum of the CDs was also found with increasing Ca(OH)(2) content, which could be attributed to the increasing of the energy gaps for the CDs. The highly photoluminescent CDs obtained (quantum yield: 86%) were used to cultivate fluorescent carnations by a water culture method, while the results of fluorescence microscopy analysis indicated that the CDs had entered the plant tissue structure.
引用
收藏
页数:10
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