Diphosphine complexes of nickel(II) are efficient catalysts for the polymerization and oligomerization of ethylene: Steric activation and ligand backbone effects

被引:73
|
作者
Dennett, JNL
Gillon, AL
Heslop, K
Hyett, DJ
Fleming, JS
Lloyd-Jones, CE
Orpen, AG
Pringle, PG
Wass, DF
Scutt, JN
Weatherhead, RH
机构
[1] Univ Bristol, Sch Chem, Bristol, Avon, England
[2] BP Chem Ltd, Sunbury On Thames, Middx, England
关键词
D O I
10.1021/om0494014
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Nickel(II) complexes of ligands of the type Ar2PCH2PAr2 and 1,2-Ar2PC6H4PAr2 (Ar = ortho-substituted phenyl) are active catalysts for polymerization and oligomerization of ethylene.
引用
收藏
页码:6077 / 6079
页数:3
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