Efficiency and durability of protective treatments on cultural heritage copper corrosion layers

被引:11
|
作者
Apchain, Emilande [1 ,2 ]
Neff, Delphine [1 ]
Gallien, Jean-Paul [1 ]
Nuns, Nicolas [3 ]
Berger, Pascal [4 ]
Noumowe, Albert [2 ]
Dillmann, Philippe [1 ]
机构
[1] Univ Paris Saclay, CEA Saclay, LAPA IRAMAT, NIMBE,CEA,CNRS, Gif Sur Yvette, France
[2] Univ Cergy Pontoise, L2MGC, 5 Mail Gay Lussac, F-95031 Neuville Sur Oise, France
[3] Univ Artois, Univ Lille, IMEC Inst Michel Eugene Chevreul, CNRS,INRA,Cent Lille,ENSCL,FR 2638, F-59000 Lille, France
[4] Univ Paris Saclay, CEA Saclay, CNRS, LEEL,NIMBE,CEA, Gif Sur Yvette, France
关键词
Copper; Copper alloys; Atmospheric corrosion; Protective treatments; Microcrystalline wax; Decanoate solution;
D O I
10.1016/j.corsci.2021.109319
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
To protect copper artefacts of the cultural heritage from atmospheric degradation protective treatment must be applied. Two types of protective treatments: microcrystalline wax (Cosmollo?d wax) and decanoate solution (HC10) were tested. Two aspects were considered: the penetration of the treatments in the corrosion layers, and its durability. Equivalent efficiencies for both treatments were demonstrated. The penetration of the treatments seems to depend essentially on its application mode. Re-corrosion experiments of treated samples under immersion in D2O demonstrate that the efficiency and the durability with time or after water leaching depend on the penetration of the treatments in the corrosion layers.
引用
收藏
页数:12
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