New uniform algorithm to predict reversed phase retention values under different gradient conditions

被引：0
|
作者：
Wang, LX [1 ]
Zhang, LF [1 ]
Xiao, HB [1 ]
Liang, XM [1 ]
机构：
[1] Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116012, Peoples R China
来源：
ANALYTICA CHIMICA ACTA | 2003年 / 476卷 / 01期
关键词：
reversed phase HPLC; retention parameter; algorithm; gradient elution;
D O I：
暂无
中图分类号：
O65 [分析化学];
学科分类号：
070302 ; 081704 ;
摘要：
A new numerical emulation algorithm was established to calculate retention parameters in RP-HPLC with several retention times under different linear or nonlinear binary gradient elution conditions and further predict the retention time under any other binary gradient conditions. A program was written according to this algorithm and nine solutes were used to test the program. The prediction results were excellent. The maximum relative error of predicted retention time was less than 0.45%. (C) 2002 Elsevier Science B.V. All rights reserved.
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页码：123 / 129
页数：7
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