Spectroscopic properties of Gd3+-doped fluorozirconate glass

被引：72
|
作者：
Binnemans, K
Gorller-Walrand, C
Adam, JL
机构：
[1] Katholieke Univ Leuven, Dept Chem, Coordinat Chem Div, B-3001 Heverlee, Belgium
[2] Univ Rennes 1, Lab Verres & Ceram, UMR CNRS 6512, F-35042 Rennes, France
来源：
CHEMICAL PHYSICS LETTERS | 1997年 / 280卷 / 3-4期
关键词：
D O I：
10.1016/S0009-2614(97)01126-3
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The optical absorption and MCD spectrum of gadolinium-doped ZBLAN fluorozirconate glass were recorded at room temperature. The induced electric dipole contributions to the experimental dipole strengths were parametrized in terms of phenomenological Judd-Ofelt intensity parameters. The parameter set obtained by a standard least-squares fitting procedure is: Omega(2) = (3.35 +/- 0.62) X 10(-20) cm(2), Omega(6) = (2.81 +/- 0.08) X 10(-20) cm(2), and Omega(4), is indeterminate. Special attention is given to the characteristic spectroscopic properties of the Gd3+ ion. (C) 1997 Elsevier Science B.V.
引用
收藏
页码：333 / 338
页数：6
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