Catalytic Performance of Divanadium-Substituted Molybdophosphate Acid, H5PMo10V2O40, in Liquid-Phase Esterification of Hexanoic Acid

被引：3
|
作者：
Bamoharram, Fatemeh F. [1 ]
Heravi, Majid M. [2 ]
Roshani, Mina [1 ]
Mir, Hamzeh [1 ]
机构：
[1] Islamic Azad Univ, Mashhad Branch, Dept Chem, Mashhad, Iran
[2] Alzahra Univ, Sch Sci, Dept Chem, Tehran, Iran
来源：
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 2009年 / 184卷 / 12期
关键词：
Catalyst; esterification; ethylhexanoate; heteropolyacid; hexanoic acid; vanadium (V)-substituted heteropolymolybdates; ONE-POT SYNTHESIS; RECYCLABLE CATALYST; ACETIC-ACID; 12-MOLYBDOPHOSPHORIC ACID; AROMATIC-ALDEHYDES; HETEROPOLY ACIDS; CARBOXYLIC-ACIDS; GREEN; EFFICIENT; OXIDATION;
D O I：
10.1080/10426500802625784
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Divanadium-substituted molybdophosphate acid, H5PMo10V2O40, efficiently catalyzes the synthesis of ethylhexanoate from hexanoic acid and ethanol at reflux temperature and under solventless conditions. Comparison of H5PMo10V2O40 with the other heteropolyacids showed that this catalyst gives the highest total yield of ethylhexanoate. The effects of the molar ratio of acid: alcohol, reaction times, and temperatures were studied.
引用
收藏
页码：3119 / 3125
页数：7
相关论文
共 50 条
  • [21] OXYBROMINATION CATALYZED BY THE HETEROPOLYANION COMPOUND H5PMO10V2O40 IN AN ORGANIC MEDIUM - SELECTIVE PARA-BROMINATION OF PHENOL
    NEUMANN, R
    ASSAEL, I
    JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1988, (19) : 1285 - 1287
  • [22] Preparation of H5PMo10V2O40 catalyst immobilized on spherical carbon and its application to the vapor-phase 2-propanol conversion reaction
    Kyung Won La
    Heesoo Kim
    Ji Chul Jung
    Joohyung Lee
    Dong Ryul Park
    Sang Hee Lee
    In Kyu Song
    Korean Journal of Chemical Engineering, 2008, 25 : 710 - 713
  • [23] Preparation of H5PMo10V2O40 catalyst immobilized on spherical carbon and its application to the vapor-phase 2-propanol conversion reaction
    La, Kyung Won
    Kim, Heesoo
    Jung, Ji Chul
    Lee, Joohyung
    Park, Dong Ryul
    Lee, Sang Hee
    Song, In Kyu
    KOREAN JOURNAL OF CHEMICAL ENGINEERING, 2008, 25 (04) : 710 - 713
  • [24] Preparation of H5PMo10V2O40 (PMo10V2) catalyst immobilized on nitrogen-containing mesoporous carbon (N-MC) and its application to the methacrolein oxidation
    Kim, Heesoo
    Jung, Ji Chul
    Park, Dong Ryul
    Baeck, Sung-Hyeon
    Song, In Kyu
    APPLIED CATALYSIS A-GENERAL, 2007, 320 (159-165) : 159 - 165
  • [25] An efficient photocatalyst based on H5PMo10V2O40/UiO-66-NH2 for direct hydroxylation of benzene to phenol by H2O2
    Jia, Xu
    Wang, Fuying
    Wen, Hao
    Zhang, Liuxue
    Jiao, Shuyan
    Wang, Xiulian
    Pei, Xinyi
    Xing, Shuzhou
    RSC ADVANCES, 2022, 12 (45) : 29433 - 29439
  • [26] H5PMo10V2O40/SBA-15催化剂的制备及其催化性能
    刘蕊
    强亮生
    马晶
    李寒阳
    唐冬雁
    无机化学学报, 2009, 25 (10) : 1779 - 1784
  • [27] Benzyl Alcohol Oxidation over H5PMo10V2O40 Catalyst Chemically Immobilized on Sulfur-containing Mesoporous Carbon
    Gim, Min Yeong
    Kang, Tae Hun
    Choi, Jung Ho
    Song, In Kyu
    KOREAN CHEMICAL ENGINEERING RESEARCH, 2016, 54 (03): : 419 - 424
  • [28] H5PMo10V2O40 immobilized on functionalized chloromethylated polystyrene by electrostatic interactions: a highly efficient and recyclable heterogeneous catalyst for hydroxylation of benzene
    Wang, Hefang
    Fang, Luping
    Yang, Yongfang
    Zhang, Li
    Wang, Yanji
    CATALYSIS SCIENCE & TECHNOLOGY, 2016, 6 (22) : 8005 - 8015
  • [29] Oxidative desulfurization of diesel by potato based-carbon as green support for H5PMo10V2O40: Efficient composite nanorod catalyst
    Rafiee, Ezzat
    Joshaghani, Mohammad
    Abadi, Parvaneh Ghaderi-Shekhi
    JOURNAL OF SAUDI CHEMICAL SOCIETY, 2017, 21 (05) : 599 - 609
  • [30] Mechanism of the Divanadium-Substituted Polyoxotungstate [γ-1,2-H2SiV2W10O40]4- Catalyzed Olefin Epoxidation by H2O2: A Computational Study
    Kuznetsov, Aleksey E.
    Geletii, Yurii V.
    Hill, Craig L.
    Morokuma, Keiji
    Musaev, Djamaladdin G.
    INORGANIC CHEMISTRY, 2009, 48 (05) : 1871 - 1878
12345