Acid-base properties of some zeolites and their activity in the decomposition of n-hexane

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Tsuchiya, S
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O64 [物理化学(理论化学)、化学物理学];
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070304 ; 081704 ;
摘要
Since zeolites are typical acid-base catalysts, their acid-base properties are of great importance in investigating the catalytic decomposition of hydrocarbons. Three methods - titration temperature-programmed desorption, and characterization by test reaction - are employed to measure acid-base properties. In this study, n-hexane was used as a model hydrocarbon and its decomposition over HY, HCeY, HSmY, and HCuY zeolites was investigated. Depending on the metal exchanged, n-hexane conversion and product distribution were observed to vary in the higher conversion region. The relation between product distribution and the acid-base properties of the zeolites are discussed.
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页码:535 / 542
页数:8
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