Synthesis and properties of palladium(I) carbonyl chlorides

被引：3
|
作者：
Fedoseev, I. V. [1 ]
Gordeev, A. S. [1 ]
机构：
[1] Bauman State Tech Univ, Kaluga Branch, Kaluga, Russia
来源：
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2007年 / 52卷 / 01期
关键词：
D O I：
10.1134/S0036023607010020
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Palladium(I) carbonyl chloride (PdCOCl)(n) has been synthesized by the effect of CO on PdCl2 in the presence of trace water. Anionic palladium(I) carbonyl chloride has been synthesized during treatment of ethanol-based or acetone-based solutions of H2PdCI4 containing small amounts of water; it has been isolated from the solution as the salt Cs-2[Pd-2(CO)(2)Cl-4]. IR-spectra, X-ray diffraction patterns, and thermogravimetry data on synthesized palladium(I) carbonyl complexes are presented.
引用
收藏
页码：7 / 9
页数：3
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