Synthesis and properties of palladium(I) carbonyl chlorides

被引：3
|
作者：
Fedoseev, I. V. [1 ]
Gordeev, A. S. [1 ]
机构：
[1] Bauman State Tech Univ, Kaluga Branch, Kaluga, Russia
来源：
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2007年 / 52卷 / 01期
关键词：
D O I：
10.1134/S0036023607010020
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Palladium(I) carbonyl chloride (PdCOCl)(n) has been synthesized by the effect of CO on PdCl2 in the presence of trace water. Anionic palladium(I) carbonyl chloride has been synthesized during treatment of ethanol-based or acetone-based solutions of H2PdCI4 containing small amounts of water; it has been isolated from the solution as the salt Cs-2[Pd-2(CO)(2)Cl-4]. IR-spectra, X-ray diffraction patterns, and thermogravimetry data on synthesized palladium(I) carbonyl complexes are presented.
引用
收藏
页码：7 / 9
页数：3
相关论文
共 50 条
  • [1] Synthesis and properties of palladium(I) carbonyl chlorides
    I. V. Fedoseev
    A. S. Gordeev
    Russian Journal of Inorganic Chemistry, 2007, 52 : 7 - 9
  • [2] SYNTHESIS AND STRUCTURE OF TETRANUCLEAR PALLADIUM(I) CARBONYL CLASTERS
    STROMNOVA, TA
    KUZMINA, LG
    VARGAFTIK, MN
    MAZO, GY
    STRUCHKOV, YT
    MOISEEV, II
    BULLETIN OF THE ACADEMY OF SCIENCES OF THE USSR DIVISION OF CHEMICAL SCIENCE, 1978, 27 (03): : 624 - 627
  • [3] Palladium(I) Carbonyl Complexes
    Stromnova, T. A.
    Moiseev, I. I.
    RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 1998, 24 (04) : 227 - 241
  • [4] Synthesis and some properties of heteronuclear platinum and palladium carbonyl clusters
    I. V. Fedoseev
    N. S. Gerasimova
    A. Yu. Loginova
    Russian Journal of Inorganic Chemistry, 2010, 55 : 186 - 189
  • [5] Synthesis and Some Properties of Heteronuclear Platinum and Palladium Carbonyl Clusters
    Fedoseev, I. V.
    Gerasimova, N. S.
    Loginova, A. Yu.
    RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2010, 55 (02) : 186 - 189
  • [6] Palladium(I) and palladium(0) carbonyl bromide complexes
    Kulik, AV
    Temkin, ON
    Bruk, LG
    Zavodnik, VE
    Belsky, VK
    Minin, VV
    RUSSIAN CHEMICAL BULLETIN, 2005, 54 (06) : 1391 - 1397
  • [7] Palladium(I) and palladium(0) carbonyl bromide complexes
    A. V. Kulik
    O. N. Temkin
    L. G. Bruk
    V. E. Zavodnik
    V. K. Belsky
    V. V. Minin
    Russian Chemical Bulletin, 2005, 54 : 1391 - 1397
  • [8] SYNTHESIS AND PROPERTIES OF STABLE PALLADIUM(O) CARBONYL COMPLEXES CONTAINING TRIPHENYLPHOSPHINE
    KUDO, K
    HIDAI, M
    UCHIDA, Y
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1971, 33 (03) : 393 - &
  • [9] SYNTHESIS AND CATALYTIC PROPERTIES OF PROTONATED CARBONYL-PHOSPHINE PALLADIUM COMPLEXES
    MINKOV, AI
    EFIMOV, OA
    EREMENKO, NK
    KLIMENKO, EB
    BULLETIN OF THE ACADEMY OF SCIENCES OF THE USSR DIVISION OF CHEMICAL SCIENCE, 1987, 36 (09): : 1926 - 1930
  • [10] FORMATION OF PALLADIUM(II) AND PALLADIUM(I) CARBONYL HALO COMPLEXES
    DELLAMICO, DB
    CALDERAZZO, F
    ZANDONA, N
    INORGANIC CHEMISTRY, 1984, 23 (02) : 137 - 140
12345