Mononuclear and dinuclear trimethylplatinum(IV) iodide complexes of 3-substituted pyridines

被引：5

作者：

Ghosh, Biswa Nath ^{[1
]}

Schlecht, Sabine ^{[2
]}

Bauza, Antonio ^{[3
]}

Frontera, Antonio ^{[3
]}

机构：

[1] Veer Surendra Sai Univ Technol, Dept Chem, Burla 768018, Odisha, India

[2] Justus Liebig Univ, Inst Anorgan & Analyt Chem, Heinrich Buff Ring 58, D-35392 Giessen, Germany

[3] Univ Illes Balears, Dept Chem, Crta De Valldemossa Km 7-5, Palma De Mallorca 07122, Baleares, Spain

来源：

NEW JOURNAL OF CHEMISTRY | 2017年 / 41卷 / 09期

关键词：

CRYSTAL-STRUCTURE; REDUCTIVE ELIMINATION; HALIDE-COMPLEXES; LIGANDS; HYDROGELATION; PYRIDAZINE; ACTIVATION; PROGRAM; SHIFTS;

D O I：

10.1039/c7nj00337d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of tetrameric trimethylplatinum(IV) iodide with an excess of 3-substituted pyridines in chloroform afforded mononuclear complexes, [PtMe3L2I] (L = 3-CNpy, 3-Brpy, 3-MeOpy, 3-Mepy and 3-Etpy). The complexes were characterized by H-1 NMR, CHN analysis and X-ray single crystal structure analysis. The mononuclear complexes undergo reaction with trimethylplatinum(IV) iodide in chloroform to form the corresponding dinuclear forms (both syn and anti). A comparison of both the mononuclear and dinuclear forms in solution for a particular pyridine substituent has been studied in detail with the help of H-1 NMR spectroscopy, ably supported by DFT computational studies. The investigation further shows the influence of the pyridine substituent on controlling the mode of the reaction. The crystal structures of two dinuclear complexes, syn-[PtMe3(3-CNpy)I](2) and anti-[PtMe3(3-Brpy)I](2), have also been described here.

引用

页码：3498 / 3507

页数：10

共 50 条

[31] 2,2′:6′,2"-Terpyridine Trimethylplatinum(IV) Iodide Complexes as Bifunctional Halogen Bond Acceptors
Ghosh, Biswa Nath
Lahtinen, Manu
Kalenius, Elina
Mal, Prasenjit
Rissanen, Kari
CRYSTAL GROWTH & DESIGN, 2016, 16 (05) : 2527 - 2534
[32] SYNTHESES AND DYNAMIC NUCLEAR-MAGNETIC-RESONANCE STUDIES OF COMPLEXES OF TRIMETHYLPLATINUM(IV) IODIDE WITH DITELLUROETHER CHELATE LIGANDS
ABEL, E
ORRELL, KG
SCANLAN, SP
STEPHENSON, D
KEMMITT, T
LEVASON, W
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1991, : 591 - 595
[33] CARBON-13 NUCLEAR MAGNETIC RESONANCE STUDIES OF 3-SUBSTITUTED PYRIDINES
RETCOFSKY, HL
FRIEDEL, RA
JOURNAL OF PHYSICAL CHEMISTRY, 1968, 72 (01): : 290 - +
[34] REGIOSPECIFIC AMINATION OF 3-SUBSTITUTED PYRIDINES USING IMIDOYL CHLORIDE FUNCTIONALIZED POLYSTYRENE
ABRAMOVITCH, RA
WANG, YX
HETEROCYCLES, 1987, 26 (08) : 2065 - 2068
[35] Antimicrobial and antioxidative activities of 1-adamantylthio derivatives of 3-substituted pyridines
Prachayasittikul, Supaluk
Suksrichavalit, Thummaruk
Isarankura-Na-Ayudhya, Chartchalerm
Ruchirawat, Somsak
Prachayasittikul, Virapong
EXCLI JOURNAL, 2008, 7 : 63 - 70
[36] SYNTHESIS OF 3-SUBSTITUTED PYRAZOLO[1,5-A]-PYRIDINES BY ELECTROPHILIC REACTIONS
MIKI, Y
YAGI, S
HACHIKEN, H
IKEDA, M
HETEROCYCLES, 1994, 38 (08) : 1881 - 1887
[37] ARYLPYRIDINES .1. ORIENTATION IN THE REACTION OF PHENYLLITHIUM WITH SOME 3-SUBSTITUTED PYRIDINES
ABRAMOVITCH, RA
GIAM, CS
NOTATION, AD
CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1960, 38 (06): : 761 - 771
[38] SYNTHESIS AND ANTIVIRAL ACTIVITY OF 3-SUBSTITUTED IMIDAZO[1,2-A]PYRIDINES
ELHAKMAOUI, A
GUEIFFIER, A
MILHAVET, JC
BLACHE, Y
CHAPAT, JP
CHAVIGNON, O
TEULADE, JC
SNOECK, R
ANDREI, G
DECLERCQ, E
BIOORGANIC & MEDICINAL CHEMISTRY LETTERS, 1994, 4 (16) : 1937 - 1940
[39] RHODANINATO-SUBSTITUTED AND 3-SUBSTITUTED RHODANINE COMPLEXES OF PALLADIUM AND PLATINUM
MOERS, FG
LANGHOUT, JP
RECUEIL DES TRAVAUX CHIMIQUES DES PAYS-BAS, 1970, 89 (12): : 1237 - &
[40] Syntheses and structures of 1,2,3-substituted cyclopentadienyl titanium(IV) complexes
Joe, DJ
Lee, BY
Shin, DM
BULLETIN OF THE KOREAN CHEMICAL SOCIETY, 2005, 26 (02) : 233 - 237

← 1 2 3 4 5 →