Crystal Structure and Electrochemical, Fluorescent and Magnetic Properties of a New Complex [Ag(2,2′-bipy)(C14H9O3)•(C14H10O3)

被引：0
|
作者：
Li Wei [1 ,2 ]
Li Chang-Hong [3 ]
Yang Ying-Qun [2 ]
Li Heng-Feng [1 ]
机构：
[1] Cent S Univ, Sch Mat Sci & Engn, Changsha 410083, Hunan, Peoples R China
[2] Hengyang Normal Univ, Dept Chem & Mat Sci, Hengyang 421008, Peoples R China
[3] Hunan Inst Technol, Sch Mat Sci & Engn, Hengyang 421002, Peoples R China
来源：
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY | 2014年 / 33卷 / 11期
关键词：
silver(I) complex; crystal structure; electrochemical; fluorescent and magnetic properties; COORDINATION POLYMER; ACID;
D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A novel silver(I) complex [Ag(2,2'-bipy)(C14H9O3)]center dot(C14H10O3) has been synthesized with 2-benzoylbenzoic acid as the ligand. Crystal data for the title complex: monoclinic, space group Cc, a = 27.4089(13), b = 10.2897(5), c = 12.0024(6) angstrom, beta = 111.864(4), M-r = 715.49, V = 3141.5(3) angstrom(3), D-c = 1.513 g/cm(3), Z = 4, mu(MoK alpha) = 0.694 min(-1), F(000) 1456, the final R= 0.0473 and wR = 0.1146. In the title complex, the central Ag(I) ion is located in a triangular coordination environment. The electron transfer is quasi-reversible in the electrode reaction and it shows a strong emission peak in the range of 495 similar to 520 nm under 502 nm excitation. In addition, it displays diamagnetic property from 3 to 300 K.
引用
收藏
页码：1593 / 1596
页数：4
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