Synthesis and Fluorescent and Magnetic Properties of a New Europium Complex Eu(C20H14O3N)3 (2,2′-bipy)(H2O)•H2O

被引：0
|
作者：
Yang Ying-Qun [1 ,2 ,3 ]
Kuang Yun-Fei [1 ,2 ,3 ]
Zhu Xiao-Ming [1 ,2 ,3 ]
机构：
[1] Hunan Prov Coll, Key Lab Funct Met Organ Cpds Hunan Prov, Hengyang 421008, Peoples R China
[2] Hunan Prov Coll, Key Lab Funct Organometall Mat, Hengyang 421008, Peoples R China
[3] Hengyang Normal Univ, Dept Chem & Mat Sci, Hengyang 421008, Peoples R China
来源：
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY | 2021年 / 40卷 / 04期
关键词：
europium(III) complex; crystal structure; fluorescent and magnetic properties; 3-DIMENSIONAL LANTHANIDE COMPLEXES; CRYSTAL-STRUCTURES; ACID; LUMINESCENT;
D O I：
10.14102/j.cnki.0254-5861.2011-2969
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new europium(III) complex Eu(C20H14O3N)(3) (2,2'-bipy)(H2O)center dot H2O has been synthesized with 2-diphenylanine carbonyl benzoic acid and 2,2'-bipyridine as ligands. Crystal data for the complex are as follows: triclinic, space group P (1) over bar, a = 11.3334(5), b = 16.0883(7), c = 17.0116(8) angstrom, alpha = 70.411(4)degrees, beta= 82.435(4)degrees, gamma = 85.095(4)degrees, V = 2894.0(2) angstrom(3) , D-c = 1.484 g/cm(3) , Z = 2, mu = 1.15 mm(-1) , F(000) = 1320 and the final R= 0.0447 and wR = 0.0578. The Eu(III) ion is coordinated by nine atoms to give a monocapped square antiprism coordination geometry. The complex shows two intense fluorescence emission bands arising from the transitions of Eu3+ : D-5(0) -> F-7(1) (592 nm) and D-5(0) -> F-7(2) (616 nm), respectively. Also reported is the magnetic property of the complex. The complex exhibits antiferromagnetism in the temperature range of 300 similar to 2 K.
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收藏
页码：507 / 511
页数：5
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