Catalytic Enantio- and Diastereoselective Alkylations with Cyclic Sulfamidates

被引：36

作者：

Moss, Thomas A. ^{[2
]}

Alonso, Beatriz ^{[1
]}

Fenwick, David R. ^{[3
]}

Dixon, Darren J. ^{[1
]}

机构：

[1] Univ Oxford, Dept Chem, Chem Res Lab, Oxford OX1 3TA, England

[2] Univ Manchester, Sch Chem, Manchester M13 9PL, Lancs, England

[3] Pfizer Global Res & Dev, Sandwich, Kent, England

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2010年 / 49卷 / 03期

基金：

英国工程与自然科学研究理事会;

关键词：

alkylation; contiguous stereocenters; phase-transfer catalysis; ring-opening reactions; sulfur heterocycles; PHASE-TRANSFER CATALYSIS; QUATERNARY AMMONIUM-SALTS; ALPHA-AMINO-ACIDS; BETA-KETO-ESTERS; ASYMMETRIC ALKYLATION; CONSTRUCTION; PRECURSORS; REACTIVITY; LACTAMS; STEREOCENTERS;

D O I：

10.1002/anie.200905329

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) Open for business: The enantio- and diastereoselective nucleophilic ring opening of five-membered and six-membered cyclic sulfamidates under asymmetric phase-transfer catalysis is presented. A range of pro-nucleophiles have been successfully alkylated in good yields and in good to excellent enantioselectivites. © 2010 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：568 / 571

页数：4

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