Sol-gel synthesis and characterization of silica supported nickel ferrite catalysts for dry reforming of methane

被引:54
|
作者
Benrabaa, Rafik [1 ,2 ]
Loefberg, Axel [3 ]
Caballero, Jesus Guerrero [3 ]
Bordes-Richard, Elisabeth [3 ]
Rubbens, Annick [3 ]
Vannier, Rose-Noelle [3 ]
Boukhlouf, Hamza [1 ,4 ]
Barama, Akila [1 ]
机构
[1] USTHB, Fac Chim, Lab Mat Catalyt & Catalyse Chim Organ, Bab Ezzouar 16111, Alger, Algeria
[2] Univ 20 Aout Skikda, Fac Technol, Dept Petrochim & Genie Proc, Skikda, Algeria
[3] Univ Lille 1, Unite Catalyse & Chim Solide, UMR CNRS 8181, F-59655 Villeneuve Dascq, France
[4] Sonatrach, Inst Algerien Petr, Les Platanes Filfila 21101, Skikda, Algeria
关键词
NiFe2O4; Sol-gel method; Isopropanol decomposition; Dry reforming of methane; OXIDATION; NANOPARTICLES; BASICITY; BEHAVIOR; ACIDITY; OXIDES; SPINEL;
D O I
10.1016/j.catcom.2014.09.019
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Silica-supported NiFe2O4 spinet was prepared by sol-gel method using tetramethyl orthosilicate as a precursor of silica. B.E.T., XRD, MEB-EDS, TEM, XPS and Raman scattering techniques were used for its characterization. The reducibility by hydrogen was investigated by TPR and HT-XRD. These properties are compared to those of unsupported NiFe2O4. Both acidic and redox sites were found by studying the decomposition of isopropanol. First experiments in the dry reforming of methane by CO2 showed that owing to more acidic properties supporting NiFe2O4 on silica provides a more active and selective catalyst that seems less prone to coking. (C) 2014 Elsevier B.V. All rights reserved.
引用
收藏
页码:127 / 131
页数:5
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