C-H and C-F bond activation reactions of pentafluorostyrene at rhodium complexes

被引：6

作者：

Xu, Conghui ^{[1
]}

Talavera, Maria ^{[1
]}

Sander, Stefan ^{[1
]}

Braun, Thomas ^{[1
]}

机构：

[1] Humboldt Univ, Dept Chem, Brook Taylor Str 2, D-12489 Berlin, Germany

来源：

DALTON TRANSACTIONS | 2019年 / 48卷 / 43期

关键词：

MARKOVNIKOV-SELECTIVE HYDROBORATION; CARBON-FLUORINE BONDS; ASYMMETRIC HYDROBORATION; CATALYZED HYDROBORATION; EFFICIENT CATALYST; FACILE ACCESS; BORYL COMPLEX; USEFUL TOOL; B-H; REACTIVITY;

D O I：

10.1039/c9dt03371h

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The rhodium(i) complexes [Rh(Bpin)(PEt3)(3)] (1), [Rh(H)(PEt3)(3)] (5) and [Rh(Me)(PEt3)(3)] (14) were employed in reactions with pentafluorostyrene affording coordination of the olefin and C-F or C-H bond activation. Control of the reaction conditions allowed for selective activation reactions at different positions at the fluorinated aromatic ring. The rhodacycle trans-[Rh(F)(CH2CH2(2-C6F4))(PEt3)(2)] (7) was identified as an intermediate for an activation at the 2-position. Reactivity studies of the latter with CO led to the generation of trans-[Rh(F)(CH2CH2C6F4)(CO)(PEt3)(2)] (10). Stoichiometric and catalytic hydroboration reactions were achieved using complexes 1 or 5 as catalysts.

引用

页码：16258 / 16267

页数：10

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