The preparation and crystal structure of (dppe)(CO)3Re-OC(O)O-Re(CO)3(dppe)

被引：8
|
作者：
Mandal, SK
Ho, DM
Li, GQ
Orchin, M [1 ]
机构：
[1] Univ Cincinnati, Dept Chem, Cincinnati, OH 45221 USA
[2] Morgan State Univ, Dept Chem, Baltimore, MD 21251 USA
[3] Princeton Univ, Dept Chem, Princeton, NJ 08544 USA
来源：
POLYHEDRON | 1998年 / 17卷 / 04期
关键词：
rhenium; 1,2-bis(diphenylphosphino)ethane; rhenium carboxylate complex; bridging carbonato complex; crystal structure;
D O I：
10.1016/S0277-5387(97)00356-2
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The title compound is readily prepared from the rhenium carboxylate, (dppe) (CO)(3)ReC(O)OCH3, by prolonged stirring of a solution of the carboxylate in benzene/H2O or THF/H2O. The reaction involves the unusual in situ conversion of Re-C bonds to Re-O bonds. The X-ray structure of the title compound shows that the mu(2) eta(2)-carbonato ligand is present in the symmetrical syn, syn conformation in the solid state in contrast to the alternate syn, anti geometry reported for the related complex, (diars)(CO)(3)ReOC(O)ORe(CO)(3)(diars). (C) 1998 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码：607 / 611
页数：5
相关论文
共 50 条
  • [31] Synthesis of trans-[Mo(O)(F)(dppe)(2)](BF4), trans-[Mo(O)(OH)(dppe)(2)](ClO4), and trans-[Mo(O)(2)(dppe)(2)].2L (L=H2O, CH3OH, CH3CH2OH, CH3CHOHCH3). Crystal structure of trans-[Mo(O)(2)(dppe)(2)].2CH(3)OH
    Bendix, J
    Birkedal, H
    Bogevig, A
    INORGANIC CHEMISTRY, 1997, 36 (13) : 2702 - +
  • [32] The synthesis, spectroscopic characterization, crystal and molecular structure of [ReBr3(NO)(dppe)]0.60[ReBr4(dppe)]0.40
    Dziegielewski, JO
    Machura, B
    Malecki, J
    Bartczak, TJ
    Czurak, W
    POLISH JOURNAL OF CHEMISTRY, 2000, 74 (02) : 191 - 198
  • [33] Syntheses, characterization and catalysts of (dppe)Rh(mu-CO)(2)M(CO)(3)
    Shao, CP
    Wang, JY
    Yang, XZ
    Guo, HF
    CHINESE CHEMICAL LETTERS, 1995, 6 (06) : 519 - 520
  • [34] Crystal chemistry of RE(CO3)OH
    Tahara, Takeshi
    Nakai, Izumi
    Miyawaki, Ritsuro
    Matsubara, Satoshi
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE, 2007, 222 (07): : 326 - 334
  • [35] ACETYLACETONATO AS A BRIDGING K(O),K(O') LIGAND - X-RAY STRUCTURE OF [(MN(CO)3(DPPE))2(MU-ACAC)]CLO4
    ALVAREZ, B
    BOIS, C
    JEANIN, Y
    MIGUEL, D
    RIERA, V
    INORGANIC CHEMISTRY, 1993, 32 (17) : 3783 - 3785
  • [36] Thermochemical studies on RE2O2CO3 (RE = Gd, Nd) decomposition
    Shirsat, AN
    Kaimal, KNG
    Bharadwaj, SR
    Das, D
    JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 2005, 66 (06) : 1122 - 1127
  • [37] COMPOUNDS WITH VANADIUM-CHALKOGEN AND CHROMIUM-CHALKOGEN MULTIPLE BONDS CRYSTAL-STRUCTURES OF (MU-SE)[V(CO)3(DPPE)]2 AND (MU-TE)[V(CO)3(DPPE)]2
    ALBRECHT, N
    HUBENER, P
    BEHRENS, U
    WEISS, E
    CHEMISCHE BERICHTE-RECUEIL, 1985, 118 (10): : 4059 - 4067
  • [38] Paramagnetic triangular rhenium sulfide cluster [Re3S4(Dppe)3(NCS)3]Br
    P. A. Petrov
    M. Yu. Afonin
    D. Yu. Naumov
    A. S. Bogomyakov
    S. N. Konchenko
    Russian Journal of Coordination Chemistry, 2014, 40 : 200 - 204
  • [39] Paramagnetic Triangular Rhenium Sulfide Cluster [Re3S4(Dppe)3(NCS)3]Br
    Petrov, P. A.
    Afonin, M. Yu.
    Naumov, D. Yu.
    Bogomyakov, A. S.
    Konchenko, S. N.
    RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2014, 40 (04) : 200 - 204
  • [40] Structure analysis of Co/Re superlattice grown on an Al2O3 (110) substrate
    Xu, WT
    Charlton, T
    De Long, LE
    Lederman, D
    CONTINUOUS NANOPHASE AND NANOSTRUCTURED MATERIALS, 2004, 788 : 609 - 613
12345