Lipase-catalyzed reactions in ionic liquids

被引:525
|
作者
Lau, RM
van Rantwijk, F
Seddon, KR
Sheldon, RA
机构
[1] Delft Univ Technol, Organ Chem & Catalysis Lab, NL-2628 BL Delft, Netherlands
[2] Queens Univ Belfast, Quill Ctr, Belfast BT9 5AG, Antrim, North Ireland
关键词
D O I
10.1021/ol006732d
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
[GRAPHICS] Candida antarctica lipase was shown to catalyze alcoholysis, ammoniolysis, and perhydrolysis reactions using the ionic liquids 1-butyl-3-methylimidazolium tetrafluoroborate or hexafluorophosphate as reaction media. Reaction rates were generally comparable with, or better than, those observed in organic media.
引用
收藏
页码:4189 / 4191
页数:3
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