7-Phosphanorbornenium Borohydrides: A Powerful Route to Functional Secondary Phosphine-Borane Complexes

被引：3
|
作者：
Tian, Rongqiang [1 ,2 ]
Mathey, Francois [1 ]
机构：
[1] Nanyang Technol Univ, Div Chem & Biol Chem, Sch Phys & Math Sci, Singapore 637371, Singapore
[2] Zhengzhou Univ, Dept Chem, Int Phosphorus Lab, Zhengzhou 450052, Peoples R China
来源：
ORGANOMETALLICS | 2010年 / 29卷 / 08期
关键词：
CATALYTIC ASYMMETRIC REACTIONS; SMALL PHOSPHORUS-HETEROCYCLES; RING-OPENING POLYMERIZATION; LIGANDS;
D O I：
10.1021/om100053d
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The reaction of phosphanorbornenium triflates with sodium borohydride gives the secondary phosphine borane complexes by reductive cleavage of the two P C bonds of the bridge. This route is compatible with functionalities such as Cl, CN, CO(2)Et, and Th.
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页码：1873 / 1874
页数：2
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