7-Phosphanorbornenium Borohydrides: A Powerful Route to Functional Secondary Phosphine-Borane Complexes

被引：3
|
作者：
Tian, Rongqiang [1 ,2 ]
Mathey, Francois [1 ]
机构：
[1] Nanyang Technol Univ, Div Chem & Biol Chem, Sch Phys & Math Sci, Singapore 637371, Singapore
[2] Zhengzhou Univ, Dept Chem, Int Phosphorus Lab, Zhengzhou 450052, Peoples R China
来源：
ORGANOMETALLICS | 2010年 / 29卷 / 08期
关键词：
CATALYTIC ASYMMETRIC REACTIONS; SMALL PHOSPHORUS-HETEROCYCLES; RING-OPENING POLYMERIZATION; LIGANDS;
D O I：
10.1021/om100053d
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The reaction of phosphanorbornenium triflates with sodium borohydride gives the secondary phosphine borane complexes by reductive cleavage of the two P C bonds of the bridge. This route is compatible with functionalities such as Cl, CN, CO(2)Et, and Th.
引用
收藏
页码：1873 / 1874
页数：2
相关论文
共 30 条
  • [1] PHOSPHINE-BORANE COMPLEXES - DIRECT USE IN ASYMMETRIC CATALYSIS
    BRISSET, H
    GOURDEL, Y
    PELLON, P
    LECORRE, M
    TETRAHEDRON LETTERS, 1993, 34 (28) : 4523 - 4526
  • [2] Synthesis of phosphine-borane complexes of P-heterocycles
    Keglevich, G
    Ujszaszy, K
    Szollosy, A
    Ludanyi, K
    Toke, L
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1996, 516 (1-2) : 139 - 145
  • [3] NATURE OF COORDINATE BOND IN PHOSPHINE-BORANE COMPLEXES - INOR
    DAMASCO, MC
    COWLEY, AH
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1970, (SEP): : 65 - &
  • [4] A highly efficient general synthesis of phosphine-borane complexes
    McNulty, J
    Zhou, YH
    TETRAHEDRON LETTERS, 2004, 45 (02) : 407 - 409
  • [5] STUDY OF DONOR-ACCEPTOR BOND IN PHOSPHINE-BORANE COMPLEXES
    COWLEY, AH
    DAMASCO, MC
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1971, 93 (25) : 6815 - &
  • [6] Synthesis and dehydrocoupling reactivity of iron and ruthenium phosphine-borane complexes
    Lee, Kajin
    Clark, Timothy J.
    Lough, Alan J.
    Manners, Ian
    DALTON TRANSACTIONS, 2008, (20) : 2732 - 2740
  • [7] Deprotection techniques for phosphine-borane complexes: Methods and extraction coefficients
    Williams, DBG
    Lombard, H
    PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 2002, 177 (12) : 2799 - 2803
  • [8] Deprotection techniques for phosphine-borane complexes: Methods and extraction coefficients
    Williams, DBG
    Lombard, H
    Van Niekerk, M
    Coetzee, PR
    PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 2002, 177 (8-9) : 2115 - 2116
  • [9] Synthesis of functionalized p-heterocycles including phosphine-borane complexes
    Keglevich, G
    Toke, L
    Ujszaszy, KG
    Szollosy, A
    PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 1996, 109 (1-4) : 457 - 460
  • [10] Intracellular disulfide reduction by phosphine-borane complexes: Mechanism of action for neuroprotection
    Niemuth, Nicholas J.
    Thompson, Alex F.
    Crowe, Megan E.
    Lieven, Christopher J.
    Levin, Leonard A.
    NEUROCHEMISTRY INTERNATIONAL, 2016, 99 : 24 - 32
123