N-Alkylacrylamide copolymers with (meth)acrylamide derivatives of cholic acid:: synthesis and thermosensitivity

被引：48
|
作者：
Avoce, D [1 ]
Liu, HY [1 ]
Zhu, XX [1 ]
机构：
[1] Univ Montreal, Dept Chim, Montreal, PQ H3C 3J7, Canada
来源：
POLYMER | 2003年 / 44卷 / 04期
关键词：
N-alkylacrylamide copolymers; bile acids; thermosensitive polymers;
D O I：
10.1016/S0032-3861(02)00868-6
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Copolymers of N-alkylacrylamides with acrylamide or methacrylamide derivatives of cholic acid have been prepared to obtain copolymers with desired thermosensitivity and enhanced hydrophilicity. The thermosensitivity of these copolymers depends on their chemical composition as studied by microcalorimetry, differential scanning calorimetry and UV-visible spectroscopy. The lower critical solution temperature and the enthalpy change of the phase separation process of the copolymers in water decreased with increasing content of the bile acid residues in the polymers. (C) 2002 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码：1081 / 1087
页数：7
相关论文
共 50 条
  • [31] Synthesis and characterization of block copolymers of styrene-maleic acid with acrylamide and N,N-dimethylacrylamide
    Khaojanta, Thidarat
    Kalaithong, Wichaya
    Somsunan, Runglawan
    Punyamoonwongsa, Patchara
    Mahomed, Anisa
    Topham, Paul D.
    Tighe, Brian J.
    Molloy, Robert
    POLYMER ENGINEERING AND SCIENCE, 2022, 62 (06): : 2031 - 2046
  • [32] Synthesis, Characterization and Antibacterial Application of Copolymers Based on N,N-Dimethyl Acrylamide and Acrylic Acid
    Nakan, Ulantay
    Bieerkehazhi, Shayahati
    Tolkyn, Balgyn
    Mun, Grigoriy A.
    Assanov, Mukhit
    Nursultanov, Merey E.
    Rakhmetullayeva, Raikhan K.
    Toshtay, Kainaubek
    Negim, El-Sayed
    Ydyrys, Alibek
    MATERIALS, 2021, 14 (20)
  • [33] THE SYNTHESIS OF WATER-SOLUBLE BIOLOGICALLY-ACTIVE COPOLYMERS OF ACRYLAMIDE AND SULFONYLAMIDINES OF (METH)ACRYLIC SERIES
    ABRAMOVA, LI
    TITOVA, OM
    MICHURIN, AA
    ZILBERMAN, EN
    VYSOKOMOLEKULYARNYE SOEDINENIYA SERIYA A & SERIYA B, 1994, 36 (12): : 2084 - 2087
  • [34] Application of allyl derivatives of cholic acid for the synthesis of macrocyclic structures
    Czajkowska, D
    Morzycki, JW
    POLISH JOURNAL OF CHEMISTRY, 2006, 80 (04) : 663 - 666
  • [35] Synthesis and Biological Evaluation of Cholic Acid Tagged Piperazine Derivatives
    Alshawabkeh, Dima W.
    Rasras, Anas J.
    Abushattal, Saqr
    Al Zubi, Mohammad S.
    Shakdofa, Mohamad M.
    Younes, Eyad A.
    Al-Qawasmeh, Raed A.
    CURRENT ORGANIC CHEMISTRY, 2024, 28 (01) : 65 - 73
  • [36] Copolymers of 1-vinylimidazole and (meth)acrylic acid: Synthesis and polyelectrolyte properties
    Annenkov, VV
    Danilovtseva, EN
    Tenhu, H
    Aseyev, V
    Hirvonen, SP
    Mikhaleva, AI
    EUROPEAN POLYMER JOURNAL, 2004, 40 (06) : 1027 - 1032
  • [37] Copolymers of 1-vinylimidazole and (meth)acrylic acid: Synthesis and polyelectrolyte properties
    Annenkov, V.V. (annenkov@home.isu.ru), 1600, Elsevier Ltd (40):
  • [38] RAFT Emulsion Polymerization of Styrene Using a Poly((N,N-dimethyl acrylamide)-co-(N-isopropyl acrylamide)) mCTA: Synthesis and Thermosensitivity
    Nieswandt, Katharina
    Georgopanos, Prokopios
    Held, Martin
    Sperling, Evgeni
    Abetz, Volker
    POLYMERS, 2022, 14 (01)
  • [39] SYNTHESIS OF CHOLIC-ACID DERIVATIVES FOR FORMATION OF MOLECULAR RECOGNITION COMPOUNDS
    LIAO, RF
    HSIEH, HP
    BURROWS, CJ
    EVANS, S
    VENANZI, CA
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1991, 202 : 57 - ORGN
  • [40] Synthesis and Swelling/De-swelling Behavior of Core-Shell Type Gel Consisting of Two Different Poly(N-alkylacrylamide) Gel Layers
    Iizawa, Takashi
    Terao, Akihiro
    Ohuchida, Machiko
    Matsuura, Yoshinobu
    Onohara, Yukio
    POLYMER JOURNAL, 2007, 39 (11) : 1177 - 1184
12345